caa a22 4500 465755127 CHVBK 20180323111845.0 cr unu---uuuuu 170327e19900101xx s 000 0 eng 10.1007/BF00503861 doi (NATIONALLICENCE)springer-10.1007/BF00503861 Extension of an improved one-fluid conformal solution theory to real fluid mixtures with large size differences [Elektronische Daten] [M. Huber, J. Ely] Conformal solution theories have been shown to be inadequate as the size ratio of the molecules in a mixture increases. We present an improved van der Waals-1 fluid conformal solution theory which incorporates a correction term developed using statistical mechanical perturbation theory. The correction addresses the effect of different size molecules on the Helmholtz free energy of the mixture. Results of the new model are compared with other conformal solution theories for model Lennard-Jones systems. We also show how to extend the model to perform computations on real fluid mixtures. Results for selected hydrocarbon mixtures are given. Plenum Publishing Corporation, 1990 conformal solution theory nationallicence corresponding states nationallicence Lennard-Jones mixtures nationallicence Huber M. Thermophysics Division, National Institute of Standards and Technology, 80303, Boulder, Colorado, USA aut Ely J. Thermophysics Division, National Institute of Standards and Technology, 80303, Boulder, Colorado, USA aut International Journal of Thermophysics Kluwer Academic Publishers-Plenum Publishers 11/1(1990-01-01), 87-96 0195-928X 11:1<87 1990 11 10765 https://doi.org/10.1007/BF00503861 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00503861 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Huber M. Thermophysics Division, National Institute of Standards and Technology, 80303, Boulder, Colorado, USA aut NATIONALLICENCE 700 1- Ely J. Thermophysics Division, National Institute of Standards and Technology, 80303, Boulder, Colorado, USA aut NATIONALLICENCE 773 0- International Journal of Thermophysics Kluwer Academic Publishers-Plenum Publishers 11/1(1990-01-01), 87-96 0195-928X 11:1<87 1990 11 10765 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer