caa a22 4500 465755836 CHVBK 20180323111846.0 cr unu---uuuuu 170327e19900901xx s 000 0 eng 10.1007/BF00503578 doi (NATIONALLICENCE)springer-10.1007/BF00503578 Thermodynamic and transport properties of 1, 2-dichloroethane [Elektronische Daten] [R. Malhotra, W. Price, L. Woolf, A. Easteal] (p, V, T) data for dichloroethane (DCE) have been obtained at 278.15, 288.15, 298.15, 313.15, 323.15, and 338.15 K for pressures either slightly below the freezing pressure or up to a maximum of 280 M Pa, together with densities at 0.1 MPa. A high-pressure self-centering falling-body viscometer method has been used to measure shear viscosities at 278.15, 288.15, 298.15, 313.15, and 323.15 K for pressures either slightly below the freezing pressure or up to a maximum of 330 MPa. Self-diffusion coefficients for DCE are reported at 278.15, 288.15, 298.15, and 313.15 K for maximum pressures up to 300 MPa. Isothermal compressibilities, isobaric expansivities, and internal pressures have been evaluated from the volumetric data. The shear viscosities and self-diffusion coefficients have been interpreted in terms of a modified rough hard-spheres theory. The anomalous behavior observed for p-V-T, shear viscosities, and self diffusion at higher temperatures and pressures is suspected to be the result of temperature and pressure altering the population ratio of the two molecular conformers, trans and gauche. Plenum Publishing Corporation, 1990 compressibility nationallicence dichloroethane nationallicence diffusion nationallicence high pressure nationallicence p, V, T , data nationallicence rough hard sphere nationallicence viscosity nationallicence Malhotra R. Atomic and Molecular Physics Laboratories, Research School of Physical Sciences, The Australian National University, Canberra, A.C.T., Australia aut Price W. Atomic and Molecular Physics Laboratories, Research School of Physical Sciences, The Australian National University, Canberra, A.C.T., Australia aut Woolf L. Atomic and Molecular Physics Laboratories, Research School of Physical Sciences, The Australian National University, Canberra, A.C.T., Australia aut Easteal A. Chemistry Department, The University of Auckland, Auckland, New Zealand aut International Journal of Thermophysics Kluwer Academic Publishers-Plenum Publishers 11/5(1990-09-01), 835-861 0195-928X 11:5<835 1990 11 10765 https://doi.org/10.1007/BF00503578 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00503578 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Malhotra R. Atomic and Molecular Physics Laboratories, Research School of Physical Sciences, The Australian National University, Canberra, A.C.T., Australia aut NATIONALLICENCE 700 1- Price W. Atomic and Molecular Physics Laboratories, Research School of Physical Sciences, The Australian National University, Canberra, A.C.T., Australia aut NATIONALLICENCE 700 1- Woolf L. Atomic and Molecular Physics Laboratories, Research School of Physical Sciences, The Australian National University, Canberra, A.C.T., Australia aut NATIONALLICENCE 700 1- Easteal A. Chemistry Department, The University of Auckland, Auckland, New Zealand aut NATIONALLICENCE 773 0- International Journal of Thermophysics Kluwer Academic Publishers-Plenum Publishers 11/5(1990-09-01), 835-861 0195-928X 11:5<835 1990 11 10765 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer