caa a22 4500 465766099 CHVBK 20180323111914.0 cr unu---uuuuu 170327e19900301xx s 000 0 eng 10.1007/BF02544329 doi (NATIONALLICENCE)springer-10.1007/BF02544329 Glyceroamidothiophosphates of cholecalciferol (Vitamin D3) [Elektronische Daten] [Stephan Stamatov, Salo Gronowitz] The hexamethyltriamide of phosphorous acid activated by the addition of iodine at the optimum molar ratio 1.05∶0.05 was used as a phosphorylating reagent to synthesize cholecalciferyl-3-0-(N,N-dimethylamido)thiophosphate derivatives of 1,3-benzylidene-rac-glycerol, 1,2-isopropylidene-rac-glycerol, 1,3-dioleoyl-rac-glycerol, and 1,2-dioleoyl-rac-glycerol in a one-pot procedure in high overall yields (81-86%). The compounds represent new model types of phospholipid structures which, in addition to glycerol and a steroid fragment, contain a biologically important linkage other than an oxygen-phosphorus bond. American Oil Chemists' Society (AOCS), 1985 Stamatov Stephan Department of Chemical Technology, University of Plavdiv, 24 Tsar Assen Street, 4000, Plovdiv, Bulgaria aut Gronowitz Salo Division of Organic Chemistry 1, University of Lund, Chemical Center, Box 124, 221 00, Lund, Sweden aut Lipids Springer-Verlag 25/3(1990-03-01), 149-151 0024-4201 25:3<149 1990 25 11745 https://doi.org/10.1007/BF02544329 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02544329 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Stamatov Stephan Department of Chemical Technology, University of Plavdiv, 24 Tsar Assen Street, 4000, Plovdiv, Bulgaria aut NATIONALLICENCE 700 1- Gronowitz Salo Division of Organic Chemistry 1, University of Lund, Chemical Center, Box 124, 221 00, Lund, Sweden aut NATIONALLICENCE 773 0- Lipids Springer-Verlag 25/3(1990-03-01), 149-151 0024-4201 25:3<149 1990 25 11745 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer