caa a22 4500 465775187 CHVBK 20180323111939.0 cr unu---uuuuu 170327e19900201xx s 000 0 eng 10.1007/BF01032231 doi (NATIONALLICENCE)springer-10.1007/BF01032231 The rhodium-catalysed methanolysis of aryl acetates and of the hexafluorophosphate anion [Elektronische Daten] [Jane Dunlop, Roy Houghton] Summary: In nitromethane, the methanolysis of aryl acetates is catalysed by the tetrafluoroborate and hexafluorophosphate salts of the (η 5-ethyltetramethylcyclopentadienyl) (η 6-benzen)rhodium(III) cation. Under the conditions of the methanolysis, the anion of the latter salt reacts with methanol to give dimethyl phosphorofluoridate. The hydrogen fluoride formed also in this reaction is thought to be responsible for the greater efficiency of the hexafluorophosphate salt as a catalyst for the methanolysis. Chapman and Hall Ltd., 1990 Dunlop Jane School of Chemistry and Applied Chemistry, University of Wales College of Cardiff, CF1 3TB, Cardiff, UK aut Houghton Roy School of Chemistry and Applied Chemistry, University of Wales College of Cardiff, CF1 3TB, Cardiff, UK aut Transition Metal Chemistry Kluwer Academic Publishers 15/1(1990-02-01), 48-50 0340-4285 15:1<48 1990 15 11243 https://doi.org/10.1007/BF01032231 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01032231 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Dunlop Jane School of Chemistry and Applied Chemistry, University of Wales College of Cardiff, CF1 3TB, Cardiff, UK aut NATIONALLICENCE 700 1- Houghton Roy School of Chemistry and Applied Chemistry, University of Wales College of Cardiff, CF1 3TB, Cardiff, UK aut NATIONALLICENCE 773 0- Transition Metal Chemistry Kluwer Academic Publishers 15/1(1990-02-01), 48-50 0340-4285 15:1<48 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer