caa a22 4500 465775217 CHVBK 20180323111939.0 cr unu---uuuuu 170327e19900201xx s 000 0 eng 10.1007/BF01032226 doi (NATIONALLICENCE)springer-10.1007/BF01032226 Medium effect in the base hydrolysis of pentaamminebromocobalt(III) ion [Elektronische Daten] [Vladislav Holba, Ol'ga Grančiěová] Summary: The effect of organic cosolvent on the rate constant of the base hydrolysis of pentaamminebromocobalt(III) ion was investigated in mixtures of H2O with MeOH, EtOH,i-PrOH,t-BuOH, and dioxane. The thermodynamic transfer functions, corresponding to the transfer of reactants and activated complex from water to the solvent mixtures, were evaluated from kinetic measurements and from solubilities of the complex salt. The experimental results are in good agreement with a dissociative mechanismvia the conjugate base. Chapman and Hall Ltd., 1990 Holba Vladislav Department of Physical Chemistry, Faculty of Science, Comenius University, 84215, Bratislava, Czechoslovakia aut Grančiěová Ol'ga Department of Physical Chemistry, Faculty of Science, Comenius University, 84215, Bratislava, Czechoslovakia aut Transition Metal Chemistry Kluwer Academic Publishers 15/1(1990-02-01), 27-30 0340-4285 15:1<27 1990 15 11243 https://doi.org/10.1007/BF01032226 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01032226 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Holba Vladislav Department of Physical Chemistry, Faculty of Science, Comenius University, 84215, Bratislava, Czechoslovakia aut NATIONALLICENCE 700 1- Grančiěová Ol'ga Department of Physical Chemistry, Faculty of Science, Comenius University, 84215, Bratislava, Czechoslovakia aut NATIONALLICENCE 773 0- Transition Metal Chemistry Kluwer Academic Publishers 15/1(1990-02-01), 27-30 0340-4285 15:1<27 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer