caa a22 4500 465775306 CHVBK 20180323111940.0 cr unu---uuuuu 170327e19900201xx s 000 0 eng 10.1007/BF01032235 doi (NATIONALLICENCE)springer-10.1007/BF01032235 Electronic spectra and electrochemical properties of bis(dimethylglyoximato)iron(II) complexes containing axial N -heterocyclic ligands [Elektronische Daten] [Henrique Toma, Luiz Morino] Gaussian analysis of the electronic spectra of 25 bis(dimethylglyoximato)iron(II) complexes containing axialN-heterocyclic ligands are discussed and comparisons made with the spectra of the corresponding [Fe(CN)5L]3− complexes. The energies of the metal-to-axial and metal-to-equatorial ligand charge-transfer transitions exhibit opposite trends, correlating with the electronic properties of the axial ligands, and with the redox potentials of the FeII/FeIII couple. Chapman and Hall Ltd., 1990 Toma Henrique Instituto de Quimica, Universidade de Sao Paulo Caixa, Postal 20780, Såo Paulo, SP, Brazil aut Morino Luiz Instituto de Quimica, Universidade de Sao Paulo Caixa, Postal 20780, Såo Paulo, SP, Brazil aut Transition Metal Chemistry Kluwer Academic Publishers 15/1(1990-02-01), 66-70 0340-4285 15:1<66 1990 15 11243 https://doi.org/10.1007/BF01032235 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01032235 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Toma Henrique Instituto de Quimica, Universidade de Sao Paulo Caixa, Postal 20780, Såo Paulo, SP, Brazil aut NATIONALLICENCE 700 1- Morino Luiz Instituto de Quimica, Universidade de Sao Paulo Caixa, Postal 20780, Såo Paulo, SP, Brazil aut NATIONALLICENCE 773 0- Transition Metal Chemistry Kluwer Academic Publishers 15/1(1990-02-01), 66-70 0340-4285 15:1<66 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer