caa a22 4500 465775470 CHVBK 20180323111940.0 cr unu---uuuuu 170327e19901201xx s 000 0 eng 10.1007/BF01040782 doi (NATIONALLICENCE)springer-10.1007/BF01040782 The solid state and solution chemistry of dichlorobis(α-picoline)-cobalt(II) [Elektronische Daten] [Linia Jacobs, Cornelins van Vuuren] Summary: The thermal decomposition of [CoCl2(α-pic)2] was investigated over the 108°C to 222°C range and the Intennediates CoCl2(α-pic) (s) and CoCl2 (s) were observed, with the evolution of (α-pic) (g). Quantitative thermodynamic and kinetic data were obtained by performing dynamic and isothermal studies on the complex Additional thermodynamic data were obtained by studying the CoCl2/α-pic system in acetone. The effect of the methylsubstituent on the metal-donor-N bond as well as on the thermodynamic quantities were discussed. Chapman and Hall Ltd, 1990 Jacobs Linia Department of Chemistry, University of South Africa, P.O. Box 392, Pretoria, S. Africa aut van Vuuren Cornelins Department of Chemistry, University of Pretoria, Pretoria, S. Africa aut Transition Metal Chemistry Kluwer Academic Publishers 15/6(1990-12-01), 486-489 0340-4285 15:6<486 1990 15 11243 https://doi.org/10.1007/BF01040782 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01040782 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Jacobs Linia Department of Chemistry, University of South Africa, P.O. Box 392, Pretoria, S. Africa aut NATIONALLICENCE 700 1- van Vuuren Cornelins Department of Chemistry, University of Pretoria, Pretoria, S. Africa aut NATIONALLICENCE 773 0- Transition Metal Chemistry Kluwer Academic Publishers 15/6(1990-12-01), 486-489 0340-4285 15:6<486 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 465156908 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer