caa a22 4500 465775578 CHVBK 20180323111940.0 cr unu---uuuuu 170327e19900601xx s 000 0 eng 10.1007/BF01038382 doi (NATIONALLICENCE)springer-10.1007/BF01038382 Dichloro bis(η5) molybdenum catalysed reduction of organic halides by sodium borohydride [Elektronische Daten] [Guo-qiang Chen, Shao-tian Wang, Xun-jun Zhou] Summary: Dichloro bis(η5) molybdenum catalyses the reduction of organic halides by sodium borohydride smoothly and selectively. The reactions with representative organic monohalides and polyhalides are investigated. The ease of reduction depends on the structure of the halide and the solvent used. alkoxycarbonyl and cyano groups are unattacked in the reaction. An oxidative addition-reductive elimination mechanism is tentatively suggested. Chapman and Hall Ltd., 1990 Chen Guo-qiang Chemistry Department, Hangzhou University, Hangzhou Zhejiang, P.R. China aut Wang Shao-tian Chemistry Department, Hangzhou University, Hangzhou Zhejiang, P.R. China aut Zhou Xun-jun Chemistry Department, Hangzhou University, Hangzhou Zhejiang, P.R. China aut Transition Metal Chemistry Kluwer Academic Publishers 15/3(1990-06-01), 236-238 0340-4285 15:3<236 1990 15 11243 https://doi.org/10.1007/BF01038382 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01038382 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Chen Guo-qiang Chemistry Department, Hangzhou University, Hangzhou Zhejiang, P.R. China aut NATIONALLICENCE 700 1- Wang Shao-tian Chemistry Department, Hangzhou University, Hangzhou Zhejiang, P.R. China aut NATIONALLICENCE 700 1- Zhou Xun-jun Chemistry Department, Hangzhou University, Hangzhou Zhejiang, P.R. China aut NATIONALLICENCE 773 0- Transition Metal Chemistry Kluwer Academic Publishers 15/3(1990-06-01), 236-238 0340-4285 15:3<236 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer