caa a22 4500 465775659 CHVBK 20180323111941.0 cr unu---uuuuu 170327e19900601xx s 000 0 eng 10.1007/BF01038383 doi (NATIONALLICENCE)springer-10.1007/BF01038383 The crystal structure of tetraethylammonium aquatetracyanooxorhenate(V) [Elektronische Daten] [Walter Purcell, Andreas Roodt, Stephen Basson, Johann Leipoldt] Summary: The crystal structure of the tetraethylammonium salt of [ReO(H2O)(CN)4]− has been determined from threedimensional x-ray diffraction data. The light blue crystals are monoclinic, space group P21/m witha=8.760(1),b=9.518(5),c=11.718(1) Å, β=102.63(1)o with two molecules per unit cell. The final R value using 2009 observed reflections and anisotropic thermal parameters for all the non-hydrogen atoms was 0.038. The [ReO(H2O)(CN)4]− ion has a distorted octahedral geometry with the rhenium atom displaced by 0.30 Å out of the plane formed by the four carbon atoms of the cyano ligands towards the oxo ligand. Bond distances: Re=O=1.667(8), Re−OH2=2.142(7) and Re−C (average)=2.11(1) Å. Chapman and Hall Ltd., 1990 Purcell Walter Department of Chemistry, University of the Orange Free State, 9300, Bloemfontein, Republic of South Africa aut Roodt Andreas Department of Chemistry, University of the Orange Free State, 9300, Bloemfontein, Republic of South Africa aut Basson Stephen Department of Chemistry, University of the Orange Free State, 9300, Bloemfontein, Republic of South Africa aut Leipoldt Johann Department of Chemistry, University of the Orange Free State, 9300, Bloemfontein, Republic of South Africa aut Transition Metal Chemistry Kluwer Academic Publishers 15/3(1990-06-01), 239-241 0340-4285 15:3<239 1990 15 11243 https://doi.org/10.1007/BF01038383 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01038383 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Purcell Walter Department of Chemistry, University of the Orange Free State, 9300, Bloemfontein, Republic of South Africa aut NATIONALLICENCE 700 1- Roodt Andreas Department of Chemistry, University of the Orange Free State, 9300, Bloemfontein, Republic of South Africa aut NATIONALLICENCE 700 1- Basson Stephen Department of Chemistry, University of the Orange Free State, 9300, Bloemfontein, Republic of South Africa aut NATIONALLICENCE 700 1- Leipoldt Johann Department of Chemistry, University of the Orange Free State, 9300, Bloemfontein, Republic of South Africa aut NATIONALLICENCE 773 0- Transition Metal Chemistry Kluwer Academic Publishers 15/3(1990-06-01), 239-241 0340-4285 15:3<239 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer