caa a22 4500 465775705 CHVBK 20180323111941.0 cr unu---uuuuu 170327e19900601xx s 000 0 eng 10.1007/BF01038371 doi (NATIONALLICENCE)springer-10.1007/BF01038371 Syntheses and x-ray crystal structures of [MoO(SCH2CH2-CH2S)2]− and [Mo2O2(μ-N3)(SCH2CH2CH2S)3]−. A study of the redox behaviour of [MoO(SCH2CH2S)2]− by cyclic voltammetry using convolution analysis [Elektronische Daten] [Peter Bishop, Jonathan Dilworth, John Hutchinson, Jon Zubieta] Summary: The complexes [PPh4][MoO{S(CH2)nS}2], n=2 (1) n=3 (3), were synthesised from the MoVI dioxoprecursor complex [MoO2(butane-2,3-diolato)2] and the appropriate thiol in the presence of base. Complex (3) exhibits a square pyramidal geometry. Crystal Data: P21,0, Z=4,a=9.612(2),b=21.202(4),c=15.462(3) Å, β=103.06(1)°, V=3043.3Å3, F(000)=1364.0, 3687 reflections collected, and 1957 used in solution with R=0.058. [MoO(SCH2CH2CH2S)2]− reacts with hydrazoic acid in methanol to produce [Mo2O2(μ-N3)-(SCH2CH2CH2S)3] (5), crystal data: $$P_{2_{1} 2_{1} 2_{1} } $$ a=9.398(3),b=14.650(2),c=27.42(2) (Å), α=β=γ=90°, Z=4 V=3775.8Å3, F(000)=1872.0, 2563 reflections collected and 1244 were used in the solution with R=0.058. The complex is an asymmetric dimer with a triple bridge comprising two dithiolate sulphurs and a nitrogen of the azide ligand. Convolution analysis of the cyclic voltammetric response of complex (1) confirmed a diffusion controlled one electron reversible reduction process. Chapman and Hall Ltd., 1990 Bishop Peter Department of Chemistry and Biological Chemistry, University of Essex, C04 3SQ, Colchester, UK aut Dilworth Jonathan Department of Chemistry and Biological Chemistry, University of Essex, C04 3SQ, Colchester, UK aut Hutchinson John Department of Chemistry, State University of New York at Albany, 12222, N.Y., USA aut Zubieta Jon Department of Chemistry, State University of New York at Albany, 12222, N.Y., USA aut Transition Metal Chemistry Kluwer Academic Publishers 15/3(1990-06-01), 177-182 0340-4285 15:3<177 1990 15 11243 https://doi.org/10.1007/BF01038371 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01038371 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bishop Peter Department of Chemistry and Biological Chemistry, University of Essex, C04 3SQ, Colchester, UK aut NATIONALLICENCE 700 1- Dilworth Jonathan Department of Chemistry and Biological Chemistry, University of Essex, C04 3SQ, Colchester, UK aut NATIONALLICENCE 700 1- Hutchinson John Department of Chemistry, State University of New York at Albany, 12222, N.Y., USA aut NATIONALLICENCE 700 1- Zubieta Jon Department of Chemistry, State University of New York at Albany, 12222, N.Y., USA aut NATIONALLICENCE 773 0- Transition Metal Chemistry Kluwer Academic Publishers 15/3(1990-06-01), 177-182 0340-4285 15:3<177 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer