caa a22 4500 465776000 CHVBK 20180323111942.0 cr unu---uuuuu 170327e19901001xx s 000 0 eng 10.1007/BF01177463 doi (NATIONALLICENCE)springer-10.1007/BF01177463 Nonoyama Matsuo Department of Chemistry, Faculty of Science, Nagoya University, Chikusa, 464, Nagoya, Japan aut Cyclometallation of N, N -dimethyl-3-furancarbothioamide with palladium(II), platinum(II), ruthenium(II) and rhodium(III) [Elektronische Daten] [Matsuo Nonoyama] Summary: N, N-Dimethyl-3-furancarbothioamide (Hbft) was cyclometallated with Li2PdCl4, K2PtCl4, RuCl2(CO)3, and RhCl (PBu3)2 (PBu3=tri-n-butylphosphine) to give, respectively, PdCl(bft), PtCl(bft), RuCl(bft)(CO)2, and RhCl2 (bft)(PBu3)2. These and some of their derivatives were characterized spectroscopically. Cyclometallation occurs regioselectively at position 2 of the furan ring to give a five-membered metallaheterocycle, along with Secoordination of the thioamide group. When the position 2 of the furan ring is blocked by a methyl group,N, N-dimethyl-2-methyl-3-furancarbothioamide (Hmft) is, in similar conditions, cyclopalladated at the N−Me substituout of the thioamide group, the furan ring being left intact. Position 4 of the furan ring of both Hbft and Hmft is unreactive toward cyclometallation. Chapman and Hall Ltd., 1990 Transition Metal Chemistry Kluwer Academic Publishers 15/5(1990-10-01), 366-370 0340-4285 15:5<366 1990 15 11243 https://doi.org/10.1007/BF01177463 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01177463 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Nonoyama Matsuo Department of Chemistry, Faculty of Science, Nagoya University, Chikusa, 464, Nagoya, Japan aut NATIONALLICENCE 773 0- Transition Metal Chemistry Kluwer Academic Publishers 15/5(1990-10-01), 366-370 0340-4285 15:5<366 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer