caa a22 4500 465776051 CHVBK 20180323111942.0 cr unu---uuuuu 170327e19901001xx s 000 0 eng 10.1007/BF01177462 doi (NATIONALLICENCE)springer-10.1007/BF01177462 Structures of mixed ligand copper(II) complexes coordinating through S, O and N. E.p.r. studies [Elektronische Daten] [Madhuri Ugrankar, Bala Prabhananda] Summary: The formation of near square planar mixed ligand CuII complexes with diethyldithiocarbamate (dtc) as one of the ligands and 8-hydroxyquinolinate (Hy) or salicylaldehydate (Sal) as the second ligand by exchange reactions, has been detected by e.p.r. spectroscopy. The concentrations of the mixed ligand complexes in the reaction mixtures are small compared to those of the reactants. Six different tests were used to identify the m1=3/2,63Cu hyperfine transition of the near square planar complexes, based upon the relative concentrations of the different CuII species in the reaction mixture, ligand hyperfine structures, the "minium linewidths” observed in a temperature dependent study and the isotropic g0 estimated from the e.p.r. spectra in solution. Chapman and Hall Ltd., 1990 Ugrankar Madhuri Chemical Physics Group, Tata Institute of Fundamental Research, 400005, Bombay, India aut Prabhananda Bala Chemical Physics Group, Tata Institute of Fundamental Research, 400005, Bombay, India aut Transition Metal Chemistry Kluwer Academic Publishers 15/5(1990-10-01), 361-365 0340-4285 15:5<361 1990 15 11243 https://doi.org/10.1007/BF01177462 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01177462 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ugrankar Madhuri Chemical Physics Group, Tata Institute of Fundamental Research, 400005, Bombay, India aut NATIONALLICENCE 700 1- Prabhananda Bala Chemical Physics Group, Tata Institute of Fundamental Research, 400005, Bombay, India aut NATIONALLICENCE 773 0- Transition Metal Chemistry Kluwer Academic Publishers 15/5(1990-10-01), 361-365 0340-4285 15:5<361 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer