caa a22 4500 46577606X CHVBK 20180323111942.0 cr unu---uuuuu 170327e19900401xx s 000 0 eng 10.1007/BF01023903 doi (NATIONALLICENCE)springer-10.1007/BF01023903 Binuclear molybdenum(V) complexes with morpholin carbamate [Elektronische Daten] [Rafael Lozano, Jesús Román, Fernando de Jesús, Esteban Alarcón] Summary: Novel oxo-and sulphido-bridged molybdenum(V) complexes with morpholin carbamate as ligand, have been prepared, identified by i.r., electronic spectra, magnetic susceptibility and analytical data and assigned the formulae [Mo2O3(LL)4], [Mo2O4(LL)2], [Mo2O2S2(LL)2] and [Mo2O3S(LL)2]. The spectra are modified by introduction of sulphur atoms into the bridge system. The low magnetic moments are thought be due, at least in part, to intramolecular metal-metal interactions. A comparison of the spectra of these complexes with those of analogous morpholin dithiocarbamate compounds has been made. Chapman and Hall Ltd, 1990 Lozano Rafael Departmento de Química Inorgánica y Bioinorgánica, Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain aut Román Jesús Departmento de Química Inorgánica y Bioinorgánica, Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain aut de Jesús Fernando Departmento de Química Inorgánica y Bioinorgánica, Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain aut Alarcón Esteban Departmento de Química Inorgánica y Bioinorgánica, Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain aut Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 141-144 0340-4285 15:2<141 1990 15 11243 https://doi.org/10.1007/BF01023903 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01023903 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Lozano Rafael Departmento de Química Inorgánica y Bioinorgánica, Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain aut NATIONALLICENCE 700 1- Román Jesús Departmento de Química Inorgánica y Bioinorgánica, Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain aut NATIONALLICENCE 700 1- de Jesús Fernando Departmento de Química Inorgánica y Bioinorgánica, Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain aut NATIONALLICENCE 700 1- Alarcón Esteban Departmento de Química Inorgánica y Bioinorgánica, Facultad de Farmacia, Universidad Complutense, 28040, Madrid, Spain aut NATIONALLICENCE 773 0- Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 141-144 0340-4285 15:2<141 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer