caa a22 4500 465776086 CHVBK 20180323111942.0 cr unu---uuuuu 170327e19900401xx s 000 0 eng 10.1007/BF01023896 doi (NATIONALLICENCE)springer-10.1007/BF01023896 Crystal structure of hexacyano cobaltate(III) of caesium and tetramethylammonium: Cs[(Me)4N]2Co(CN)6 [Elektronische Daten] [Angel Morales, René Romero, Julio Rodríguez, Ramόn Hernández, José Bertrán] Summary: The structure of a novel hexacyano cobaltate(III) of Cs and tetramethylammonium (TMA), Cs(TMA)2Co(CN)6, has been determined by single crystal x-ray diffraction using Patterson and Fourier techniques, and refined by least squares to R=0.053 for 126 independent reflections. The compound is cubic with ao=12.592(2) Å, space group Fm3m, Z=4. There is a cubic network of Co−CN−Cs atoms with Co−C and C−N distances of 1.87(2) and 1.18(2) Å respectively. The bulky (TMA) cations occupy the cubic voids in this network. The C−N distance of (TMA) is 1.38(2) Å. The Me groups are oriented towards the Cs atoms and there is hindered rotation of the CH3 groups. The Hatoms occupy positions at maximum distance from the C−N triple bonds, pointing to the faces of the octants of the unit cell. Chapman and Hall Ltd, 1990 Morales Angel Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut Romero René Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut Rodríguez Julio Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut Hernández Ramόn Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut Bertrán José Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 106-107 0340-4285 15:2<106 1990 15 11243 https://doi.org/10.1007/BF01023896 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01023896 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Morales Angel Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut NATIONALLICENCE 700 1- Romero René Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut NATIONALLICENCE 700 1- Rodríguez Julio Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut NATIONALLICENCE 700 1- Hernández Ramόn Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut NATIONALLICENCE 700 1- Bertrán José Centro Nacional de Investigaciones Científicas, Apartado Postal 6990, Ctudad de la Habana aut NATIONALLICENCE 773 0- Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 106-107 0340-4285 15:2<106 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer