caa a22 4500 465776116 CHVBK 20180323111942.0 cr unu---uuuuu 170327e19900401xx s 000 0 eng 10.1007/BF01023909 doi (NATIONALLICENCE)springer-10.1007/BF01023909 The solid state chemistry of dichlorobis(pyridine)manganese(II) and dichlorobis(pyridine)nickel(II) [Elektronische Daten] [Linda Jacobs, Cornelius van Vuuren] Summary: The thermal decompositions of [MnCl2(py)2] and [NiCl2(py)2] were investigated and the following dissociation reactions were observed: [MnCl2(py)2](s)→MnCl2(py)(s)+(py)(g) [MnCl2(py)2](s)→MnCl2(s)+2(py)(g) and [NiCl2(py)2](s)→NiCl2(py)(s)+(py)(g) [NiCl2(py)2](s)→NiCl2(s)+2(py)(g). Quantitative thermodynamic as well as kinetic data were obtained by performing dynamic and isothermal studies on the complexes. The DSC studies provided evidence for the existence of the additional intermediates [Ni3Cl6(py)2] and [Mn3Cl6(py)2], which could not be obtained from the dynamic and isothermal studies. Chapman and Hall Ltd, 1990 Jacobs Linda Department of Chemistry, University of South Africa, P. O. Box 392, Pretoria, SA aut van Vuuren Cornelius Department of Chemistry, University of Pretoria, Pretoria, SA aut Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 164-169 0340-4285 15:2<164 1990 15 11243 https://doi.org/10.1007/BF01023909 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01023909 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Jacobs Linda Department of Chemistry, University of South Africa, P. O. Box 392, Pretoria, SA aut NATIONALLICENCE 700 1- van Vuuren Cornelius Department of Chemistry, University of Pretoria, Pretoria, SA aut NATIONALLICENCE 773 0- Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 164-169 0340-4285 15:2<164 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer