caa a22 4500 465776167 CHVBK 20180323111942.0 cr unu---uuuuu 170327e19900401xx s 000 0 eng 10.1007/BF01023894 doi (NATIONALLICENCE)springer-10.1007/BF01023894 Synthesis and physico-chemical characterization of coordination compounds of 3d metals with bis(hydroxylammonium)bicyclo[2.2.1]-hept-5-en-endo-2,3- cis -dicarboxylate [Elektronische Daten] [Oksana Midyanko, Vasilii Galla, Vladimir Buzash, Vukadin Leovac] Summary: The reaction of aqueous solutions of 3d metal salts with bis(hydroxylammonium) bicyclo[2.2.1]-hept-5-en-endo-2,3-cis-dicarboxylate in a 1∶2 mole ratio yielded complexes of the general formula [MnL2(NH3OH)2]·nH2O and [FeIIIL2(NH3OH)H2O]·H2O, where MII=Mn, Fe, Co, Ni, Cu and Zn, and L=bicyclo[2.2.1]-hept-5-en-endo-2,3-cis-dicarboxylate dianion. The compounds were characterized by i.r. spectra and thermal analysis. For all complexes, an octahedral structure is proposed which is formed bytrans coordination of two bidentate (OO) ligands (L) and two NH3OH+ cations attrans positions, coordinated also through oxygen atoms; and similarlytrans positions for NH3OH+ and H2O in the case of the FeIII complex. Chapman and Hall Ltd, 1990 Midyanko Oksana Faculty of Chemistry, State University, Uzhorod, USSR aut Galla Vasilii Faculty of Chemistry, State University, Uzhorod, USSR aut Buzash Vladimir Faculty of Chemistry, State University, Uzhorod, USSR aut Leovac Vukadin Faculty of Sciences, Institute of Chemistry, I. Djuričića 4, 21000, Novi Sad, Yugoslavia aut Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 96-98 0340-4285 15:2<96 1990 15 11243 https://doi.org/10.1007/BF01023894 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01023894 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Midyanko Oksana Faculty of Chemistry, State University, Uzhorod, USSR aut NATIONALLICENCE 700 1- Galla Vasilii Faculty of Chemistry, State University, Uzhorod, USSR aut NATIONALLICENCE 700 1- Buzash Vladimir Faculty of Chemistry, State University, Uzhorod, USSR aut NATIONALLICENCE 700 1- Leovac Vukadin Faculty of Sciences, Institute of Chemistry, I. Djuričića 4, 21000, Novi Sad, Yugoslavia aut NATIONALLICENCE 773 0- Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 96-98 0340-4285 15:2<96 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 465776167 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer