caa a22 4500 465776175 CHVBK 20180323111942.0 cr unu---uuuuu 170327e19900401xx s 000 0 eng 10.1007/BF01023897 doi (NATIONALLICENCE)springer-10.1007/BF01023897 Ligating characteristic of an unstable phosphorus(III) derivative diphenylisothiocyanatophosphine; Synthesis and characterization of its chelates with transition metal ions [Elektronische Daten] [Zafar Siddiqi, Abhai Chauhan, Shahla Oidwai] Summary: Diphenylisothiocyanatophosphine prepared in CHCl3 solution from Ph2PCl and AgSCN yields stable complexes with MCl2, Cu2Cl2, [Ni(Ph3P)2Cl2] or [Cu(Ph3P)3Cl] which have the stoichiometry [MLCl2], [M=Ni(1) or Cu(2)], [CuLCl](3), [Ni(Ph3P)-(Ph2PNCS)Cl2](4) and [Cu(Ph3P)(Ph2PNCS)Cl](5) respectively characterized by physicochemical methods. The>PNCS moiety retains its entity in the complexes providing both P and S as chelating centres. The geometry of the complexes has been determined from magnetic susceptibility and electronic spectral measurements. Chapman and Hall Ltd, 1990 Siddiqi Zafar Inorganic Chemistry Division, Chemistry Department, Aligarh Muslim University, 202002, Aligarh, India aut Chauhan Abhai Inorganic Chemistry Division, Chemistry Department, Aligarh Muslim University, 202002, Aligarh, India aut Oidwai Shahla Inorganic Chemistry Division, Chemistry Department, Aligarh Muslim University, 202002, Aligarh, India aut Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 108-111 0340-4285 15:2<108 1990 15 11243 https://doi.org/10.1007/BF01023897 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01023897 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Siddiqi Zafar Inorganic Chemistry Division, Chemistry Department, Aligarh Muslim University, 202002, Aligarh, India aut NATIONALLICENCE 700 1- Chauhan Abhai Inorganic Chemistry Division, Chemistry Department, Aligarh Muslim University, 202002, Aligarh, India aut NATIONALLICENCE 700 1- Oidwai Shahla Inorganic Chemistry Division, Chemistry Department, Aligarh Muslim University, 202002, Aligarh, India aut NATIONALLICENCE 773 0- Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 108-111 0340-4285 15:2<108 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer