caa a22 4500 465776205 CHVBK 20180323111942.0 cr unu---uuuuu 170327e19900401xx s 000 0 eng 10.1007/BF01023899 doi (NATIONALLICENCE)springer-10.1007/BF01023899 Complexes of copper(II) with some new thiocarbamide derivatives [Elektronische Daten] [Gaber Abu El-Reash, Fatma Taha, Gamila Badr] Summary: A new series of thiocarbamides was prepared by the reaction of benzoylisothiocyanate with various amines namely 2-aminopyridine (H2LI), 3-aminopyridine (H2LII), 2,3-diaminopyridine (H2LIII), 2,6-diaminopyridine (H2LIV), o-phenylene diamine (H2LV), p-phenylenediamine (H2LVI) and ethylene diamine (H2LVII). The copper(II) complexes of these ligands were isolated and have been characterized by elemental analyses, molar conductivities, magnetic moments and spectral (visible, i.r.) measurements. I.r. spectra show that the ligands behave as dianionic or neutral tetradentates or as monoanionic or neutral bidentates. The [Cu(HLI)Cl]2 and Cu(H2LIV)Cl2 complexes are diamagnetic and the other complexes have normal magnetic moment at room temperature. Electronic spectral analyses show that Cu2(LIV)Ac2 is planar and the other complexes are tetragonally distorted octahedral. All the complexes are non-electrolytes. Chapman and Hall Ltd, 1990 Abu El-Reash Gaber Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt aut Taha Fatma Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt aut Badr Gamila Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt aut Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 116-119 0340-4285 15:2<116 1990 15 11243 https://doi.org/10.1007/BF01023899 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01023899 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Abu El-Reash Gaber Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt aut NATIONALLICENCE 700 1- Taha Fatma Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt aut NATIONALLICENCE 700 1- Badr Gamila Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt aut NATIONALLICENCE 773 0- Transition Metal Chemistry Springer Netherlands 15/2(1990-04-01), 116-119 0340-4285 15:2<116 1990 15 11243 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer