caa a22 4500 465786669 CHVBK 20180323112011.0 cr unu---uuuuu 170327e19900701xx s 000 0 eng 10.1007/BF00298321 doi (NATIONALLICENCE)springer-10.1007/BF00298321 Stepto R. Polymer Science and Technology Group, Manchester Materials Science Centre, University of Manchester, Grosvenor Street, M1 7HS, Manchester, UK aut Gel-gel reaction in RAf and RA2+RBf polymerisations [Elektronische Daten] [R. Stepto] Summary: The amount of gel-gel reaction in RAf and RA2+RBf random polymerisations is evaluated. For a given functionality f and stoichmetric amounts of reactants, half as much gel-gel reaction occurs in RA2+RBf polymerisations by complete reaction as in RAf polymerisations. This difference is readily understandable in that the formation of a loop requirestwice as many pairs of groups to react in the former type of polymerisation as in the latter. Gel-gel reaction is necessary for the formation of the network structure at complete reaction. However, it also leads to network imperfections, viz. inelastic loops. Springer-Verlag, 1990 Polymer Bulletin Springer-Verlag 24/1(1990-07-01), 53-58 0170-0839 24:1<53 1990 24 289 https://doi.org/10.1007/BF00298321 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00298321 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Stepto R. Polymer Science and Technology Group, Manchester Materials Science Centre, University of Manchester, Grosvenor Street, M1 7HS, Manchester, UK aut NATIONALLICENCE 773 0- Polymer Bulletin Springer-Verlag 24/1(1990-07-01), 53-58 0170-0839 24:1<53 1990 24 289 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer