caa a22 4500 465787444 CHVBK 20180323112013.0 cr unu---uuuuu 170327e19901101xx s 000 0 eng 10.1007/BF00395567 doi (NATIONALLICENCE)springer-10.1007/BF00395567 Radical polymerization of N -substituted citraconimides as polymerizable 1,1,2-trisubstituted ethylenes [Elektronische Daten] [Takayuki Otsu, Jian-Zhong Yang] Summary: The radical polymerization behavior of N-substituted citraconimides, 1, 1, 2-trisubstituted ethylenic monomers, was investigated. N-Alkylcitraconimides were found to homopolymerize in bulk at 60°C to give polymers with molecular weight of 6800∼10000, except methyl and ethyl derivatives. Polymerization of N-phenylcitraconimides in benzene at 60°C or in bulk at 120°C gave polymers with relatively low molecular weight from 700 to 2000. From thermogravimetric analysis, the initial and maximum decomposition temperatures for poly(N-isopropyl-citraconimide) were 309 and 365°C, respectively, and these were lower than those for poly(N-isopropylmaleimide) by about 40°C. Springer-Verlag, 1990 Otsu Takayuki Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sugimoto, Sumiyoshi-ku, 558, Osaka, Japan aut Yang Jian-Zhong Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sugimoto, Sumiyoshi-ku, 558, Osaka, Japan aut Polymer Bulletin Springer-Verlag 24/5(1990-11-01), 475-480 0170-0839 24:5<475 1990 24 289 https://doi.org/10.1007/BF00395567 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00395567 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Otsu Takayuki Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sugimoto, Sumiyoshi-ku, 558, Osaka, Japan aut NATIONALLICENCE 700 1- Yang Jian-Zhong Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sugimoto, Sumiyoshi-ku, 558, Osaka, Japan aut NATIONALLICENCE 773 0- Polymer Bulletin Springer-Verlag 24/5(1990-11-01), 475-480 0170-0839 24:5<475 1990 24 289 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer