caa a22 4500 465787525 CHVBK 20180323112013.0 cr unu---uuuuu 170327e19900801xx s 000 0 eng 10.1007/BF00297326 doi (NATIONALLICENCE)springer-10.1007/BF00297326 Solution properties and characteristic ratio of near-monodisperse poly(tert-butyl methacrylate) [Elektronische Daten] [Anthony Karandinos, Jimmy Mays, Nikos Hadjichristidis] Summary: The dilute solution properties of six near-monodisperse samples of poly(tert-butyl methacrylate) covering the molecular weight range $$3 \times 10^4 \leqslant \bar M_w \leqslant 1.1 \times 10^6 $$ are reported. Unperturbed chain dimensions were derived from a combination of light scattering and intrinsic viscosity data. A characteristic ratio (C∞) of 12.0 was obtained in the theta solvent cyclohexane at 10°C. This C∞ value is considerably larger than the value of 8.8 reported previously for poly(n-butyl methacrylate) and reflects the greater bulkiness of the tert-butyl substituent and also, possibly, tacticity effects. Springer-Verlag, 1990 Karandinos Anthony Department of Chemistry, University of Alabama at Birmingham, 35294, Birmingham, AL, USA aut Mays Jimmy Department of Chemistry, University of Alabama at Birmingham, 35294, Birmingham, AL, USA aut Hadjichristidis Nikos Department of Chemistry, University of Athens, GR-106 80, Athens, Greece aut Polymer Bulletin Springer-Verlag 24/2(1990-08-01), 251-254 0170-0839 24:2<251 1990 24 289 https://doi.org/10.1007/BF00297326 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00297326 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Karandinos Anthony Department of Chemistry, University of Alabama at Birmingham, 35294, Birmingham, AL, USA aut NATIONALLICENCE 700 1- Mays Jimmy Department of Chemistry, University of Alabama at Birmingham, 35294, Birmingham, AL, USA aut NATIONALLICENCE 700 1- Hadjichristidis Nikos Department of Chemistry, University of Athens, GR-106 80, Athens, Greece aut NATIONALLICENCE 773 0- Polymer Bulletin Springer-Verlag 24/2(1990-08-01), 251-254 0170-0839 24:2<251 1990 24 289 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer