caa a22 4500 465787584 CHVBK 20180323112013.0 cr unu---uuuuu 170327e19900801xx s 000 0 eng 10.1007/BF00297309 doi (NATIONALLICENCE)springer-10.1007/BF00297309 Laser photocatalytic polymerization of phenylacetylene [Elektronische Daten] [Jin Pei, Shan Jun, Lu Chongxian, Zhou Yihua, Fu Kejian] Summary: The polymerization of phenylacetylene induced by ultraviolet laser (266 and 355 nm) irradiation of W(CO)6 and W(CO)6-TiCl4 in CCl4 solvent was investigated. The weight-average molecular weights of the polymers reach 105. The infrared spectra indicate that the polymers have a trans-rich conjugated double bond structure. The influence of laser energy, laser wavelength and irradiation time on the polymerization was examined. Experimental data show that laser energy and wavelength are the most effective factors. Springer-Verlag, 1990 Pei Jin Institute of Physics, Chinese Academy of Sciences, P.O. Box 603-51, 100080, Beijing, People's Republic of China aut Jun Shan Institute of Physics, Chinese Academy of Sciences, P.O. Box 603-51, 100080, Beijing, People's Republic of China aut Chongxian Lu Beijing Institute of Chemical Technology, Beijing, People's Republic of China aut Yihua Zhou National Center for Certified Reference Materials, Beijing, People's Republic of China aut Kejian Fu Institute of Physics, Chinese Academy of Sciences, P.O. Box 603-51, 100080, Beijing, People's Republic of China aut Polymer Bulletin Springer-Verlag 24/2(1990-08-01), 135-141 0170-0839 24:2<135 1990 24 289 https://doi.org/10.1007/BF00297309 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00297309 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Pei Jin Institute of Physics, Chinese Academy of Sciences, P.O. Box 603-51, 100080, Beijing, People's Republic of China aut NATIONALLICENCE 700 1- Jun Shan Institute of Physics, Chinese Academy of Sciences, P.O. Box 603-51, 100080, Beijing, People's Republic of China aut NATIONALLICENCE 700 1- Chongxian Lu Beijing Institute of Chemical Technology, Beijing, People's Republic of China aut NATIONALLICENCE 700 1- Yihua Zhou National Center for Certified Reference Materials, Beijing, People's Republic of China aut NATIONALLICENCE 700 1- Kejian Fu Institute of Physics, Chinese Academy of Sciences, P.O. Box 603-51, 100080, Beijing, People's Republic of China aut NATIONALLICENCE 773 0- Polymer Bulletin Springer-Verlag 24/2(1990-08-01), 135-141 0170-0839 24:2<135 1990 24 289 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer