caa a22 4500 465787746 CHVBK 20180323112014.0 cr unu---uuuuu 170327e19900101xx s 000 0 eng 10.1007/BF00983956 doi (NATIONALLICENCE)springer-10.1007/BF00983956 The 4-methacrylamido-2-methyl-2-butoxy-carbonyl-function as polymerizable amino-protecting group [Elektronische Daten] [Henning Rehse, Helmut Ritter] Summary: The synthesis of an highly acidic sensitive polymerizable amino-protecting group is described in the case of the N-protected model compound 4-methacryl-amido-2-methyl-2-butyl-N-p-chlorophenylcarbamate. The new monomer was homopolymerized and copolymerized by radical initiation. Kinetics of acidically induced p-chloroaniline cleavage from the monomer and polymers were followed by NMR spectroscopy. The influence of Calcium-ions and neighbouring group effects are discussed. Springer-Verlag, 1990 Rehse Henning Bergische Universität-Gesamthochschule Wuppertal, Fachbereich 9, Gausstrasse 20, D-5600, Wuppertal 1, Federal Republic of Germany aut Ritter Helmut Bergische Universität-Gesamthochschule Wuppertal, Fachbereich 9, Gausstrasse 20, D-5600, Wuppertal 1, Federal Republic of Germany aut Polymer Bulletin Springer-Verlag 23/1(1990-01-01), 1-6 0170-0839 23:1<1 1990 23 289 https://doi.org/10.1007/BF00983956 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00983956 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Rehse Henning Bergische Universität-Gesamthochschule Wuppertal, Fachbereich 9, Gausstrasse 20, D-5600, Wuppertal 1, Federal Republic of Germany aut NATIONALLICENCE 700 1- Ritter Helmut Bergische Universität-Gesamthochschule Wuppertal, Fachbereich 9, Gausstrasse 20, D-5600, Wuppertal 1, Federal Republic of Germany aut NATIONALLICENCE 773 0- Polymer Bulletin Springer-Verlag 23/1(1990-01-01), 1-6 0170-0839 23:1<1 1990 23 289 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer