caa a22 4500 46578836X CHVBK 20180323112016.0 cr unu---uuuuu 170327e19900501xx s 000 0 eng 10.1007/BF00419967 doi (NATIONALLICENCE)springer-10.1007/BF00419967 Anionic ring opening polymerization of 1-silacyclopent-3-ene [Elektronische Daten] Characterization of poly(1-sila- cis -pent-3-ene) by 1H, 13C, and 29Si NMR spectroscopy [Stephen Zhou, Young Park, Georges Manuel, William Weber] Summary: 1-Silacyclopent-3-ene (I) undergoes anionic ring opening polymerization catalyzed by methyllithium/HMPA to yield poly(1-sila-cis-pent-3-ene) (II). II was characterized by 1H, 13C, and 29Si NMR, GPC, TGA and elemental analysis. The low molecular weight of II permits end group analysis. Pyrolysis of II gives high char yields. These have been characterized by EDS. Springer-Verlag, 1990 Zhou Stephen D.P. and K.B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA aut Park Young D.P. and K.B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA aut Manuel Georges D.P. and K.B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA aut Weber William D.P. and K.B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA aut Polymer Bulletin Springer-Verlag 23/5(1990-05-01), 491-496 0170-0839 23:5<491 1990 23 289 https://doi.org/10.1007/BF00419967 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00419967 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhou Stephen D.P. and K.B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA aut NATIONALLICENCE 700 1- Park Young D.P. and K.B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA aut NATIONALLICENCE 700 1- Manuel Georges D.P. and K.B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA aut NATIONALLICENCE 700 1- Weber William D.P. and K.B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA aut NATIONALLICENCE 773 0- Polymer Bulletin Springer-Verlag 23/5(1990-05-01), 491-496 0170-0839 23:5<491 1990 23 289 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer