caa a22 4500 465788424 CHVBK 20180323112016.0 cr unu---uuuuu 170327e19900501xx s 000 0 eng 10.1007/BF00419964 doi (NATIONALLICENCE)springer-10.1007/BF00419964 Synthesis and radical polymerization of 1,1,2,2-tetracyanocyclopropylstyrene [Elektronische Daten] [Ju-Yeon Lee, H. Hall Jr.] Synopsis: An isomeric mixture (m-/p-: 70/30, mole/mole) of 1,1,2,2-tetracyanocyclopropylstyrene 2 was prepared by cyclopropane formation from bromomalononitrile and vinyl benzaldehyde. The substituted styrene compound 2 was polymerized with free radical initiator to obtain the polymers with multicyano functions in the pendant group. The resulting polymers were soluble in acetone and dimethyl sulfoxide (DMSO) and the inherent viscosities were in the range of 0.27-0.32 dL/g. Solution-cast films were clear and brittle, showing Tg value of 112°C. Springer-Verlag, 1990 Lee Ju-Yeon C.S. Marvel Laboratories, Department of Chemistry, University of Arizona, 85721, Tucson, AZ, USA aut Hall Jr. H. C.S. Marvel Laboratories, Department of Chemistry, University of Arizona, 85721, Tucson, AZ, USA aut Polymer Bulletin Springer-Verlag 23/5(1990-05-01), 471-475 0170-0839 23:5<471 1990 23 289 https://doi.org/10.1007/BF00419964 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00419964 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Lee Ju-Yeon C.S. Marvel Laboratories, Department of Chemistry, University of Arizona, 85721, Tucson, AZ, USA aut NATIONALLICENCE 700 1- Hall Jr H. C.S. Marvel Laboratories, Department of Chemistry, University of Arizona, 85721, Tucson, AZ, USA aut NATIONALLICENCE 773 0- Polymer Bulletin Springer-Verlag 23/5(1990-05-01), 471-475 0170-0839 23:5<471 1990 23 289 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer