caa a22 4500 465795676 CHVBK 20180323112037.0 cr unu---uuuuu 170327e19900101xx s 000 0 eng 10.1007/BF02631383 doi (NATIONALLICENCE)springer-10.1007/BF02631383 Hydrogenation of carboxylic acids by rhenium-osmium bimetallic catalyst [Elektronische Daten] [Koji Yoshino, Yasushi Kajiwara, Naotake Takaishi, Yoshiaki Inamoto, Jiro Tsuji] Hydrogenation of carboxylic acids to alcohols at low temperature and under low pressure was achieved by using a new catalyst system, a rhenium-osmium bimetallic catalyst. The most active catalyst was prepared by the reductionof the corresponding metal oxides with hydrogen in the presence of succinic acid. Decanoic acid was hydrogenated to decanol in high conversions at 25∼100 atm and 100∼120°C. Decane was formed as a by-product by overreduction of the alcohol. The selectivity of alcohol was improved by the addition of thiophene as a modifier of the catalyst. The American Oil Chemists' Society, 1990 Yoshino Koji Kao Institute for Fundamental Research Laboratories, Kao Corp, 2606, Akabane, Ichikai-machi, 321-34, Tochigi, Japan aut Kajiwara Yasushi Kao Institute for Fundamental Research Laboratories, Kao Corp, 2606, Akabane, Ichikai-machi, 321-34, Tochigi, Japan aut Takaishi Naotake Kao Institute for Fundamental Research Laboratories, Kao Corp, 2606, Akabane, Ichikai-machi, 321-34, Tochigi, Japan aut Inamoto Yoshiaki Kao Institute for Fundamental Research Laboratories, Kao Corp, 2606, Akabane, Ichikai-machi, 321-34, Tochigi, Japan aut Tsuji Jiro Tokyo Institute of Technology, Megro, 152, Tokyo, Japan aut Journal of the American Oil Chemists Society Springer-Verlag 67/1(1990-01-01), 21-24 0003-021X 67:1<21 1990 67 11746 https://doi.org/10.1007/BF02631383 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02631383 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yoshino Koji Kao Institute for Fundamental Research Laboratories, Kao Corp, 2606, Akabane, Ichikai-machi, 321-34, Tochigi, Japan aut NATIONALLICENCE 700 1- Kajiwara Yasushi Kao Institute for Fundamental Research Laboratories, Kao Corp, 2606, Akabane, Ichikai-machi, 321-34, Tochigi, Japan aut NATIONALLICENCE 700 1- Takaishi Naotake Kao Institute for Fundamental Research Laboratories, Kao Corp, 2606, Akabane, Ichikai-machi, 321-34, Tochigi, Japan aut NATIONALLICENCE 700 1- Inamoto Yoshiaki Kao Institute for Fundamental Research Laboratories, Kao Corp, 2606, Akabane, Ichikai-machi, 321-34, Tochigi, Japan aut NATIONALLICENCE 700 1- Tsuji Jiro Tokyo Institute of Technology, Megro, 152, Tokyo, Japan aut NATIONALLICENCE 773 0- Journal of the American Oil Chemists Society Springer-Verlag 67/1(1990-01-01), 21-24 0003-021X 67:1<21 1990 67 11746 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer