caa a22 4500 465796478 CHVBK 20180323112039.0 cr unu---uuuuu 170327e19901001xx s 000 0 eng 10.1007/BF02540418 doi (NATIONALLICENCE)springer-10.1007/BF02540418 A new method of synthesis of alkyl-glycidyl esters of dicarboxylic acids in high yields [Elektronische Daten] [S. Zlatanos, A. Sagredos] A series of new alkyl-glycidyl esters of dicarboxylic acids which could be used as PVC plasticizers were synthesized. The method adopted is a new synthetic process which can be carried out in two stages. During the first stage, the carboxylic acid anhydride reacts with the salt of the alcohol, and the sodium salt produced reacts with epichlorhydrin in the presence of a catalyst to yield an alkyl-glycidyl ester. The specific reactions give pure products in high yields. The reaction of phthalic acid bisodium salt with epichlorhydrin, as well as the reaction of phthaloyl chloride with glycidol, gave diglycidyl phthalate in 36% and 22% yields, respectively. AOCS Press, 1990 Alkyl-glycidyl esters of dicarboxylic acids nationallicence cyclic acid anhydrides nationallicence dicarboxylic acids nationallicence dicarboxylic acid chlorides nationallicence dicarboxylic acid disodium salt nationallicence dicarboxylic acid sodium salt nationallicence diglycidyl esters nationallicence epichlorhydrin nationallicence monoglycidyl esters nationallicence tetraethylammonium iodide nationallicence Zlatanos S. Laboratory of Organic Chemistry, College of Chemical Engineering, Aristotle University of Thessaloniki, Greece aut Sagredos A. Laboratory of Organic Chemistry, College of Chemical Engineering, Aristotle University of Thessaloniki, Greece aut Journal of the American Oil Chemists' Society Springer-Verlag 67/10(1990-10-01), 661-664 0003-021X 67:10<661 1990 67 11746 https://doi.org/10.1007/BF02540418 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02540418 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zlatanos S. Laboratory of Organic Chemistry, College of Chemical Engineering, Aristotle University of Thessaloniki, Greece aut NATIONALLICENCE 700 1- Sagredos A. Laboratory of Organic Chemistry, College of Chemical Engineering, Aristotle University of Thessaloniki, Greece aut NATIONALLICENCE 773 0- Journal of the American Oil Chemists' Society Springer-Verlag 67/10(1990-10-01), 661-664 0003-021X 67:10<661 1990 67 11746 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer