caa a22 4500 465796931 CHVBK 20180323112040.0 cr unu---uuuuu 170327e19900501xx s 000 0 eng 10.1007/BF02539687 doi (NATIONALLICENCE)springer-10.1007/BF02539687 Weers Jeffry Pioneering Research, Clorox Technical Center, P.O. Box 493, 94566, Pleasanton, CA aut Solubilization in mixed micelles [Elektronische Daten] [Jeffry Weers] Solubilization capacities for decane have been determined for a variety of mixed surfactant systems. Negative deviations from additivity are observed for nonionic/ionic mixtures where there are no attractive interactions between the surfactant headgroups. "Synergistic” positive deviations from additivity are observed for anionic/cationic mixtures, where strong attractive forces between the headgroups exist. The results are interpreted in terms of curvature effects using the Israelachvili, Mitchell and Ninhamv/a o l model and a model based on Laplace pressures. Data are also presented for the C12TAB/C12EO6 system which clearly shows the differences in the solubilization sites for hexanol, which solubilizes in the palisade region, and decane, which solubilizes in the micellar core. The results indicate that any future modeling will have to include surfactant-solubilizate interactions as well as surfactant-surfactant interactions. AOCS Press, 1990 Journal of the American Oil Chemists' Society Springer-Verlag 67/5(1990-05-01), 340-345 0003-021X 67:5<340 1990 67 11746 https://doi.org/10.1007/BF02539687 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02539687 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Weers Jeffry Pioneering Research, Clorox Technical Center, P.O. Box 493, 94566, Pleasanton, CA aut NATIONALLICENCE 773 0- Journal of the American Oil Chemists' Society Springer-Verlag 67/5(1990-05-01), 340-345 0003-021X 67:5<340 1990 67 11746 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer