caa a22 4500 465798438 CHVBK 20180323112045.0 cr unu---uuuuu 170327e19900901xx s 000 0 eng 10.1007/BF00795584 doi (NATIONALLICENCE)springer-10.1007/BF00795584 The electronic structure of W2Cx nonstoichiometric tungsten carbides [Elektronische Daten] [O. Khizhun, E. Zhurakovskii, Ya. Zaulichnyi] Conclusions: X-ray emission and X-ray electron spectra indicate a small transfer of charge from a tungsten atom to carbon in W2CX. With an increase in nonstoichiometry of these compounds there is an increase in density of the d-states of tungsten in the near-Fermi area. For W2CX strong hybridization of the W5d- and C2p-states is characteristic. The W4f-lines of the C-ray photoelectron spectra broaden with an increase in the number of vacant nodes in the nonmetallic sublattice, which is caused by the relative increase in the number of metal atoms found in a different energy state. Plenum Publishing Corporation, 1991 Khizhun O. Institute of Problems of Material Sciences, Academy of Sciences of the Ukrainian SSR, Ukraine aut Zhurakovskii E. Institute of Problems of Material Sciences, Academy of Sciences of the Ukrainian SSR, Ukraine aut Zaulichnyi Ya Institute of Problems of Material Sciences, Academy of Sciences of the Ukrainian SSR, Ukraine aut Soviet Powder Metallurgy and Metal Ceramics Kluwer Academic Publishers-Plenum Publishers 29/9(1990-09-01), 732-737 0038-5735 29:9<732 1990 29 11106 https://doi.org/10.1007/BF00795584 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00795584 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Khizhun O. Institute of Problems of Material Sciences, Academy of Sciences of the Ukrainian SSR, Ukraine aut NATIONALLICENCE 700 1- Zhurakovskii E. Institute of Problems of Material Sciences, Academy of Sciences of the Ukrainian SSR, Ukraine aut NATIONALLICENCE 700 1- Zaulichnyi Ya Institute of Problems of Material Sciences, Academy of Sciences of the Ukrainian SSR, Ukraine aut NATIONALLICENCE 773 0- Soviet Powder Metallurgy and Metal Ceramics Kluwer Academic Publishers-Plenum Publishers 29/9(1990-09-01), 732-737 0038-5735 29:9<732 1990 29 11106 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer