caa a22 4500 465807399 CHVBK 20180323112106.0 cr unu---uuuuu 170327e19900701xx s 000 0 eng 10.1007/BF00530432 doi (NATIONALLICENCE)springer-10.1007/BF00530432 Quantum chemical analysis of the process of reduction of nitrogen oxide by ammonia [Elektronische Daten] [O. Sychev, V. Ivasenko] We have carried out a quantum chemical analysis of the electronic structure of the nitroprusside ion [Fe(CN)5NO]2− and also the transition complex [Fe(CN)5NO· NH3]2− arising in the course of the reaction of reduction of coordinated nitrogen oxide with a nucleophile (ammonia). We consider the characteristics of the redistribution of electron density in the nitroprusside accompanying the nucleophilic attack. We discuss the role of the central iron ion and the CN-ligands during nucleophilic reduction. Plenum Publishing Corporation, 1990 Sychev O. Tomsk Polytechnical Institute, USSR aut Ivasenko V. Tomsk Polytechnical Institute, USSR aut Theoretical and Experimental Chemistry Kluwer Academic Publishers-Plenum Publishers 25/4(1990-07-01), 401-407 0040-5760 25:4<401 1990 25 11237 https://doi.org/10.1007/BF00530432 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00530432 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sychev O. Tomsk Polytechnical Institute, USSR aut NATIONALLICENCE 700 1- Ivasenko V. Tomsk Polytechnical Institute, USSR aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Kluwer Academic Publishers-Plenum Publishers 25/4(1990-07-01), 401-407 0040-5760 25:4<401 1990 25 11237 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer