caa a22 4500 465807429 CHVBK 20180323112106.0 cr unu---uuuuu 170327e19900701xx s 000 0 eng 10.1007/BF00530436 doi (NATIONALLICENCE)springer-10.1007/BF00530436 Models for spin-label macromolecule motion in the 3 cm and 2 mm ESR ranges [Elektronische Daten] [O. Poluéktov, O. Grinberg, A. Dubinskii, O. Sidorov, Ya. Lebedev] A study is presented on models for the motion of spin-label macromolecules indicated by 3 cm and 2 mm ESR spectra. Theoretical calculations are employed to simulate combination of the relative motion with transport motion (in conjunction with a macromolecule segment) for various temperature-viscosity relationships in the anisotropic Brownian diffusion of nitroxyl radicals. In that approach, one cannot match the relaxation effects in the two sets of spectra. It is concluded that there are fast relative label oscillations that do not average the g and A tensors to axisymmetric ones. Plenum Publishing Corporation, 1990 Poluéktov O. Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut Grinberg O. Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut Dubinskii A. Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut Sidorov O. Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut Lebedev Ya Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut Theoretical and Experimental Chemistry Kluwer Academic Publishers-Plenum Publishers 25/4(1990-07-01), 426-431 0040-5760 25:4<426 1990 25 11237 https://doi.org/10.1007/BF00530436 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00530436 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Poluéktov O. Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut NATIONALLICENCE 700 1- Grinberg O. Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut NATIONALLICENCE 700 1- Dubinskii A. Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut NATIONALLICENCE 700 1- Sidorov O. Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut NATIONALLICENCE 700 1- Lebedev Ya Institute of Chemical Physics, USSR Academy of Sciences, Moscow aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Kluwer Academic Publishers-Plenum Publishers 25/4(1990-07-01), 426-431 0040-5760 25:4<426 1990 25 11237 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer