caa a22 4500 465807798 CHVBK 20180323112107.0 cr unu---uuuuu 170327e19900901xx s 000 0 eng 10.1007/BF00529979 doi (NATIONALLICENCE)springer-10.1007/BF00529979 Quenching of luminescence of terbium(III) by platinum(IV) complexes [Elektronische Daten] [K. Balashev, V. Vasil'ev, O. Bordovskaya, A. Zimnyakov, G. Shagisultanova] The rate constants (kq) of the bimolecular energy-transfer reactions in systems consisting of the terbium(III) aquo complex and platinum(IV) complexes have been determined. The influence of the electronic and nuclear factors on the values of the rate constant of the reactions has been considered. It has been shown that the platinum(IV) complexes make up an adiabatic family of quenchers, while the energy-transfer reactions between terbium(III) aquo complexes are characterized by a high degree of nonadiabaticity x ∼-10−12). Estimates of the energies of the pure electronic transitions to electronically excited states of platinum(IV) complexes which are not observed spectroscopically have been obtained on the basis of the dependence of kq on the change in the free energy of the energy-transfer process. Plenum Publishing Corporation, 1990 Balashev K. A. I. Gertsen Leningrad Teachers Institute, USSR aut Vasil'ev V. A. I. Gertsen Leningrad Teachers Institute, USSR aut Bordovskaya O. A. I. Gertsen Leningrad Teachers Institute, USSR aut Zimnyakov A. A. I. Gertsen Leningrad Teachers Institute, USSR aut Shagisultanova G. A. I. Gertsen Leningrad Teachers Institute, USSR aut Theoretical and Experimental Chemistry Kluwer Academic Publishers-Plenum Publishers 25/5(1990-09-01), 568-572 0040-5760 25:5<568 1990 25 11237 https://doi.org/10.1007/BF00529979 text/html Onlinezugriff via DOI 1 brief-communication jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00529979 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Balashev K. A. I. Gertsen Leningrad Teachers Institute, USSR aut NATIONALLICENCE 700 1- Vasil'ev V. A. I. Gertsen Leningrad Teachers Institute, USSR aut NATIONALLICENCE 700 1- Bordovskaya O. A. I. Gertsen Leningrad Teachers Institute, USSR aut NATIONALLICENCE 700 1- Zimnyakov A. A. I. Gertsen Leningrad Teachers Institute, USSR aut NATIONALLICENCE 700 1- Shagisultanova G. A. I. Gertsen Leningrad Teachers Institute, USSR aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Kluwer Academic Publishers-Plenum Publishers 25/5(1990-09-01), 568-572 0040-5760 25:5<568 1990 25 11237 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer