caa a22 4500 465807933 CHVBK 20180323112108.0 cr unu---uuuuu 170327e19900101xx s 000 0 eng 10.1007/BF00943892 doi (NATIONALLICENCE)springer-10.1007/BF00943892 Mechanism of heterogeneous catalytic oxidation of acetone vapor on vanadium pentoxide [Elektronische Daten] [V. Vorotyntsev, V. Borovik, G. Golodets] We have used an extensive set of kinetic data to consider the probable reaction mechanism for the oxidation of acetone on vanadium pentoxide at 433-473 K. It is concluded that a significant part is played by the stage of the reoxidation of the catalyst surface, coupled with the transfer of oxygen during the formation of the reaction products. Computer calculations have been used to determine the best values of the rate constants of the separate stages of the proposed mechanism. Plenum Publishing Corporation, 1990 Vorotyntsev V. Pisarzhevskii Physicochemical Institute, Ukrainian SSR Academy of Sciences, Kiev aut Borovik V. Pisarzhevskii Physicochemical Institute, Ukrainian SSR Academy of Sciences, Kiev aut Golodets G. Pisarzhevskii Physicochemical Institute, Ukrainian SSR Academy of Sciences, Kiev aut Theoretical and Experimental Chemistry Kluwer Academic Publishers-Plenum Publishers 26/1(1990-01-01), 106-110 0040-5760 26:1<106 1990 26 11237 https://doi.org/10.1007/BF00943892 text/html Onlinezugriff via DOI 1 brief-communication jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00943892 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Vorotyntsev V. Pisarzhevskii Physicochemical Institute, Ukrainian SSR Academy of Sciences, Kiev aut NATIONALLICENCE 700 1- Borovik V. Pisarzhevskii Physicochemical Institute, Ukrainian SSR Academy of Sciences, Kiev aut NATIONALLICENCE 700 1- Golodets G. Pisarzhevskii Physicochemical Institute, Ukrainian SSR Academy of Sciences, Kiev aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Kluwer Academic Publishers-Plenum Publishers 26/1(1990-01-01), 106-110 0040-5760 26:1<106 1990 26 11237 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer