caa a22 4500 465808344 CHVBK 20180323112109.0 cr unu---uuuuu 170327e19900501xx s 000 0 eng 10.1007/BF00641349 doi (NATIONALLICENCE)springer-10.1007/BF00641349 Reaction of bis-η3-allylnickel complexes with allyl halides [Elektronische Daten] [V. Flid, V. Vasyukov, A. Belov] A study was carried out on the reaction between bis-η3-allylnickel complexes and various allyl halides leading to 1,5-dienes. The combination of the allyl fragments may occur either as a result of their coupling in the bis-η3-allylnickel complex or with the participation of the allyl halide. The reaction pathway is largely determined by the structure of the starting nickel complex and the yield of the coupling products increases with decreasing stability of the complexes. The structure of the allyl fragment and the nature of the halide in the allyl halide hardly affect the direction of the reaction. The rate-limiting step is the cleavage of the allyl-halide bond. Plenum Publishing Corporation, 1990 Flid V. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR aut Vasyukov V. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR aut Belov A. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR aut Theoretical and Experimental Chemistry Kluwer Academic Publishers 26/3(1990-05-01), 348-352 0040-5760 26:3<348 1990 26 11237 https://doi.org/10.1007/BF00641349 text/html Onlinezugriff via DOI 1 brief-communication jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00641349 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Flid V. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR aut NATIONALLICENCE 700 1- Vasyukov V. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR aut NATIONALLICENCE 700 1- Belov A. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Kluwer Academic Publishers 26/3(1990-05-01), 348-352 0040-5760 26:3<348 1990 26 11237 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer