caa a22 4500 465808409 CHVBK 20180323112109.0 cr unu---uuuuu 170327e19900301xx s 000 0 eng 10.1007/BF01160494 doi (NATIONALLICENCE)springer-10.1007/BF01160494 Kinetic model of concentration oscillations during the photolysis of homogeneous gaseous systems [Elektronische Daten] [V. Bykov, G. Skorobogatov] We consider the kinetics of the photolysis of a halide RX in the gas phase by a rectangular photolyzing flash, involving the 3-stage cyclic kinetic scheme $$X_1 \xrightarrow{{k_1 }}X_2 + X_4 ,X_2 \xrightarrow{{k_2 }}X_3 ,X_3 + X_4 \xrightarrow{{k_a }}X_1 $$ . For certain values of the rate constants k1, k2 and k3 oscillations in the concentrations [Xi] are observed. Particularly pronounced oscillations occur for the quantity γ = [X2] − [X3], which is used to interpret the oscillations observed previously in a study of the photodissociative iodine laser for the iodides CF3I, C3F7I and i-C3F7I. Plenum Publishing Corporation, 1990 Bykov V. Chemical Research Institute, Leningrad University, USSR aut Skorobogatov G. Chemical Research Institute, Leningrad University, USSR aut Theoretical and Experimental Chemistry Kluwer Academic Publishers 26/2(1990-03-01), 144-149 0040-5760 26:2<144 1990 26 11237 https://doi.org/10.1007/BF01160494 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01160494 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bykov V. Chemical Research Institute, Leningrad University, USSR aut NATIONALLICENCE 700 1- Skorobogatov G. Chemical Research Institute, Leningrad University, USSR aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Kluwer Academic Publishers 26/2(1990-03-01), 144-149 0040-5760 26:2<144 1990 26 11237 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer