caa a22 4500 465808417 CHVBK 20180323112109.0 cr unu---uuuuu 170327e19900301xx s 000 0 eng 10.1007/BF01160511 doi (NATIONALLICENCE)springer-10.1007/BF01160511 Quantum chemical study of the appearance of the "α-effect” in35Cl NQR spectra of chloromethylsilanes [Elektronische Daten] [L. Romanenko, R. Ponets, V. Sidorkin] We consider the connection between the electron distribution in ClCH2MX1X2X3 molecules (M = C, Si) calculated by the CNDO/2 method and the experimental35Cl NQR frequencies. We show that the ratio of the NQR frequencies for chloromethylsilanes and their organic analogs can be explained on the basis of ideas concerning the totality of induction and conjugation effects influencing the population of the orbital of the chlorine atom which participates in formation of the C-Cl bond. Plenum Publishing Corporation, 1990 Romanenko L. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR aut Ponets R. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR aut Sidorkin V. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR aut Theoretical and Experimental Chemistry Kluwer Academic Publishers 26/2(1990-03-01), 225-228 0040-5760 26:2<225 1990 26 11237 https://doi.org/10.1007/BF01160511 text/html Onlinezugriff via DOI 1 brief-communication jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01160511 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Romanenko L. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR aut NATIONALLICENCE 700 1- Ponets R. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR aut NATIONALLICENCE 700 1- Sidorkin V. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Kluwer Academic Publishers 26/2(1990-03-01), 225-228 0040-5760 26:2<225 1990 26 11237 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer