caa a22 4500 465808573 CHVBK 20180323112110.0 cr unu---uuuuu 170327e19900301xx s 000 0 eng 10.1007/BF01160514 doi (NATIONALLICENCE)springer-10.1007/BF01160514 Multiple attenuated total internal reflection spectra of ultrathin titanium oxide layers synthesized on a germanium surface [Elektronische Daten] [A. Krasovskii, V. Grigor'ev, V. Baranov, E. Edalyan] We have realized a vacuum variant for recording the multiple attenuated total internal reflection spectra of ultrathin (2-30 nm) layers of titanium dioxide directly over the course of their synthesis by the molecular lamination method on the surface of germanium single crystals. To a first approximation, there is a linear relationship between the intensity of the bands of the doublet at 890 and 820 cm−1 (respectivelyv as andv s(Ti − O) and the number of molecular lamination cycles (thickness of the synthesized layers); deviations from linearity are due to the effects of the substrate and are expressed in changes in the shape of the contour of the doubletv as/v s for thicknesses <10 nm. Redistribution of the intensity in thev as,v s bands with an increase in thickness (>20 nm) of the titanium dioxide layer is due to the content of adsorbed H2O and HCl molecules in the layer, desorption of which when the samples are heated leads to denser packing of the synthesized layers. Plenum Publishing Corporation, 1990 Krasovskii A. Leningrad Scientific-Industrial Association "Pigment”, USSR aut Grigor'ev V. Leningrad Scientific-Industrial Association "Pigment”, USSR aut Baranov V. Leningrad Scientific-Industrial Association "Pigment”, USSR aut Edalyan E. Leningrad Scientific-Industrial Association "Pigment”, USSR aut Theoretical and Experimental Chemistry Kluwer Academic Publishers 26/2(1990-03-01), 234-238 0040-5760 26:2<234 1990 26 11237 https://doi.org/10.1007/BF01160514 text/html Onlinezugriff via DOI 1 brief-communication jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01160514 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Krasovskii A. Leningrad Scientific-Industrial Association "Pigment”, USSR aut NATIONALLICENCE 700 1- Grigor'ev V. Leningrad Scientific-Industrial Association "Pigment”, USSR aut NATIONALLICENCE 700 1- Baranov V. Leningrad Scientific-Industrial Association "Pigment”, USSR aut NATIONALLICENCE 700 1- Edalyan E. Leningrad Scientific-Industrial Association "Pigment”, USSR aut NATIONALLICENCE 773 0- Theoretical and Experimental Chemistry Kluwer Academic Publishers 26/2(1990-03-01), 234-238 0040-5760 26:2<234 1990 26 11237 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer