caa a22 4500 465818528 CHVBK 20180323112129.0 cr unu---uuuuu 170327e19901101xx s 000 0 eng 10.1007/BF01374528 doi (NATIONALLICENCE)springer-10.1007/BF01374528 Chemical species conversion in condensed systems or at interfaces: quantum and classical regime of anharmonic Franck-Condon transitions [Elektronische Daten] [H. Schultz, C. Engler, W. Lorenz] Summary: The relation of quantum to classical regime of Franck-Condon transitions is investigated, focussing on transitions in diabatic, anharmonic 1D potentials of a reactive subsystem which allow for chemical bond formation and partial charge transfer. A survey of numerical results is given for the range of both regimes under different system characteristics, including the diabatic barrier height of the reactive subsystem, the transfer distance (barrier breadth), and the reduced mass (1 to ∞) of the reactive mode. Energy distribution of transition components and of state-resolved statistical lifetimes are briefly discussed. Springer-Verlag, 1990 Quantum and classical regime nationallicence Franck nationallicence Condon transitions nationallicence Diabatic anharmonic potentials nationallicence Energy distribution of transition components nationallicence Schultz H. Sektion Chemie, Universität Leipzig, DDR-7010, Leipzig, German Democratic Republic aut Engler C. Sektion Chemie, Universität Leipzig, DDR-7010, Leipzig, German Democratic Republic aut Lorenz W. Sektion Chemie, Universität Leipzig, DDR-7010, Leipzig, German Democratic Republic aut Theoretica chimica acta Springer-Verlag 77/6(1990-11-01), 369-382 0040-5744 77:6<369 1990 77 214 https://doi.org/10.1007/BF01374528 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01374528 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Schultz H. Sektion Chemie, Universität Leipzig, DDR-7010, Leipzig, German Democratic Republic aut NATIONALLICENCE 700 1- Engler C. Sektion Chemie, Universität Leipzig, DDR-7010, Leipzig, German Democratic Republic aut NATIONALLICENCE 700 1- Lorenz W. Sektion Chemie, Universität Leipzig, DDR-7010, Leipzig, German Democratic Republic aut NATIONALLICENCE 773 0- Theoretica chimica acta Springer-Verlag 77/6(1990-11-01), 369-382 0040-5744 77:6<369 1990 77 214 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer