caa a22 4500 465818749 CHVBK 20180323112129.0 cr unu---uuuuu 170327e19900301xx s 000 0 eng 10.1007/BF01114535 doi (NATIONALLICENCE)springer-10.1007/BF01114535 The dynamical crystal field model of selective vibronic coupling in d-d spectra [Elektronische Daten] [A. Ceulemans, N. Bongaerts] Summary: The dynamic crystal field operators, corresponding to the normal point-charge displacements in an octahedral complex are analyzed in detail. The strict equivalence of absolute versus relative coordinate treatments is established. The resulting formalism is applied to the intensity distribution in the vibronic side bands of the sharp line luminescence spectra ofd 3 complexes. Thereby special attention is given to the role of spin-orbit coupling and to the elastic properties of the molecular force field. Using the closure procedure, the relative intensities of the side bands may be expressed in terms of a single dynamic crystal field parameter. These expressions provide a simple rationalization of the observed vibronic selection rules, entirely within the framework of dynamic crystal field theory. Springer-Verlag, 1990 Dynamic crystal field theory nationallicence Vibronic coupling nationallicence Vibronic selectivity nationallicence d 3 Complexes nationallicence Ceulemans A. Department of Chemistry, University of Leuven, Celestijnenlaan 200F, B-3030, Leuven, Belgium aut Bongaerts N. Department of Chemistry, University of Leuven, Celestijnenlaan 200F, B-3030, Leuven, Belgium aut Theoretica chimica acta Springer-Verlag 77/2(1990-03-01), 85-109 0040-5744 77:2<85 1990 77 214 https://doi.org/10.1007/BF01114535 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01114535 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ceulemans A. Department of Chemistry, University of Leuven, Celestijnenlaan 200F, B-3030, Leuven, Belgium aut NATIONALLICENCE 700 1- Bongaerts N. Department of Chemistry, University of Leuven, Celestijnenlaan 200F, B-3030, Leuven, Belgium aut NATIONALLICENCE 773 0- Theoretica chimica acta Springer-Verlag 77/2(1990-03-01), 85-109 0040-5744 77:2<85 1990 77 214 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer