caa a22 4500 467888167 CHVBK 20180406152740.0 cr unu---uuuuu 170328e20060601xx s 000 0 eng 10.1007/s11144-006-0123-2 doi (NATIONALLICENCE)springer-10.1007/s11144-006-0123-2 Oxidation of alcohols with hydrogen peroxide catalyzed by soluble iron and osmium derivatives [Elektronische Daten] [Lidia S. Shul'pina, Dario Veghini, Aleksandr R. Kudinov, Georgiy B. Shul'pin] Summary: Osmium chloride OsCl3 efficiently catalyzes (yields of products up to 90%, turnover numbers (TON) up to 1500) the oxidation of 2-cyanoethanol with hydrogen peroxide to produce the corresponding aldehyde and acid. Oxidation of isopropanol over OsCl3 gave acetone in 58% yield. The reactions were carried out either in acetonitrile or without any solvent. The analogous iron compound FeCl3 was found to be less efficient in the oxidation of 2-cyanoethanol (yields of products up to 67%, TON up to 135). Oxidation of isopropanol in this case gave acetone (yield 53%) and acetic acid (yield 11%). Some other soluble derivatives of iron or osmium exhibited noticeably lower catalytic activity in the alcohol oxidation with H2O2. Springer-Verlag/Akadémiai Kiadó, 2006 hydrogen peroxide nationallicence Alcohols nationallicence iron complexes nationallicence osmium complexes nationallicence homogeneous catalysis nationallicence oxidation nationallicence Shul'pina Lidia S. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow 119991, Russia aut Veghini Dario Organic Fine Chemicals, Lonza Ltd.,, Visp CH-3930, Switzerland aut Kudinov Aleksandr R. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow 119991, Russia aut Shul'pin Georgiy B. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow 119991, Russia aut Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 88/1(2006-06-01), 157-163 0133-1736 88:1<157 2006 88 11144 https://doi.org/10.1007/s11144-006-0123-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-006-0123-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Shul'pina Lidia S. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow 119991, Russia aut NATIONALLICENCE 700 1- Veghini Dario Organic Fine Chemicals, Lonza Ltd.,, Visp CH-3930, Switzerland aut NATIONALLICENCE 700 1- Kudinov Aleksandr R. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow 119991, Russia aut NATIONALLICENCE 700 1- Shul'pin Georgiy B. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow 119991, Russia aut NATIONALLICENCE 773 0- Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 88/1(2006-06-01), 157-163 0133-1736 88:1<157 2006 88 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer