caa a22 4500 467888191 CHVBK 20180406152740.0 cr unu---uuuuu 170328e20060601xx s 000 0 eng 10.1007/s11144-006-0105-4 doi (NATIONALLICENCE)springer-10.1007/s11144-006-0105-4 Investigation of the HDS kinetics of dibenzotiophene and its derivatives in real gas oil [Elektronische Daten] [Zoltán Varga, Jenő Hancsók, Dénes Kalló, Árpád Stumpfc] Summary: The hydrodesulfurization (HDS) of dibenzothiophene (DBT), 4-methyl-dibenzothiophene (4 M-DBT), 4,6-dimethyldibenzothiophene (4,6 DM-DBT) and 4,6-diethyldibenzothiophene (4,6 DE-DBT) as real gas oil components on NiMo/Al2O3 catalyst was investigated. On the basis of the first order rate constants of HDS of the individual sulfur compounds calculated by both integral and differential evaluations the reactivities of the investigated compounds decreased in the order DBT >> 4 M-DBT > 4,6 DE-DBT >> 4,6 DM-DBT. Additionally, results showed that product inhibition during HDS does not take place. Springer-Verlag/Akadémiai Kiadó, 2006 gas oil nationallicence alkyl dibenzothiophenes nationallicence Hydrodesulfurization nationallicence kinetics nationallicence Varga Zoltán Department of Hydrocarbon and Coal Processing, University of Veszprém, Veszprém, P.O. Box 158, H-8201, Hungary aut Hancsók Jenő Department of Hydrocarbon and Coal Processing, University of Veszprém, Veszprém, P.O. Box 158, H-8201, Hungary aut Kalló Dénes Chemical Research Center, Institute of Chemistry, Hungarian Academy Sciences, Budapest, P.O. Box 17, H-1525, Hungary aut Stumpfc Árpád Division of Production and Trade, MOL - Hungarian Oil and Gas Co, Százhalombatta, P.O. Box 1, H-2443, Hungary aut Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 88/1(2006-06-01), 19-26 0133-1736 88:1<19 2006 88 11144 https://doi.org/10.1007/s11144-006-0105-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-006-0105-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Varga Zoltán Department of Hydrocarbon and Coal Processing, University of Veszprém, Veszprém, P.O. Box 158, H-8201, Hungary aut NATIONALLICENCE 700 1- Hancsók Jenő Department of Hydrocarbon and Coal Processing, University of Veszprém, Veszprém, P.O. Box 158, H-8201, Hungary aut NATIONALLICENCE 700 1- Kalló Dénes Chemical Research Center, Institute of Chemistry, Hungarian Academy Sciences, Budapest, P.O. Box 17, H-1525, Hungary aut NATIONALLICENCE 700 1- Stumpfc Árpád Division of Production and Trade, MOL - Hungarian Oil and Gas Co, Százhalombatta, P.O. Box 1, H-2443, Hungary aut NATIONALLICENCE 773 0- Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 88/1(2006-06-01), 19-26 0133-1736 88:1<19 2006 88 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer