caa a22 4500 46788840X CHVBK 20180406152741.0 cr unu---uuuuu 170328e20060801xx s 000 0 eng 10.1007/s11144-006-0068-5 doi (NATIONALLICENCE)springer-10.1007/s11144-006-0068-5 Kinetic behavior of benzene hydrogenation and thiophene hydrogenolysis on sulfide Ni-Mo/Al2O3 catalyst [Elektronische Daten] [Evgeniy A. Ivanov, Sergey I. Reshetnikov, Mikhail V. Sidyakin, Anatoliy N Startsev] Summary: An unsteady-state kinetic model of both benzene hydrogenation (HDA) and thiophene hydrogenolysis (HDS) on a sulfide hydrotreating catalyst Ni-Mo/Al2O3 has been developed. The model adequately describes experimental data obtained at the pressure 2 MPa, temperature 573 K and at various contact times and ratios of benzene/thiophene. The model is based on the assumption that the catalyst surface contains only one type of active sites, i.e., Ni atoms in the sulfide bimetallic species, which are responsible for both hydrogenolysis and hydrogenation reactions. Springer-Verlag/Akadémiai Kiadó, 2006 benzene hydrogenation nationallicence Transient kinetics nationallicence sulfide catalyst nationallicence Ivanov Evgeniy A. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut Reshetnikov Sergey I. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut Sidyakin Mikhail V. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut Startsev Anatoliy N. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 88/2(2006-08-01), 325-332 0133-1736 88:2<325 2006 88 11144 https://doi.org/10.1007/s11144-006-0068-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-006-0068-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ivanov Evgeniy A. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut NATIONALLICENCE 700 1- Reshetnikov Sergey I. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut NATIONALLICENCE 700 1- Sidyakin Mikhail V. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut NATIONALLICENCE 700 1- Startsev Anatoliy N. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut NATIONALLICENCE 773 0- Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 88/2(2006-08-01), 325-332 0133-1736 88:2<325 2006 88 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer