caa a22 4500 467888566 CHVBK 20180406152741.0 cr unu---uuuuu 170328e20060801xx s 000 0 eng 10.1007/s11144-006-0058-7 doi (NATIONALLICENCE)springer-10.1007/s11144-006-0058-7 Cyclopentyl decanoate and butyl cyclopentanecarboxylate conversions into ketones over solid catalyst [Elektronische Daten] [Roman Klimkiewicz, Hanna Grabowska, Ludwik Syper] Summary: Cyclopentyl n-decanoate and n-butyl cyclopentanecarboxylate were converted into ketones over heterogeneous catalyst. The transformations proceeded as parallel ones: through b-ketoesters with simultaneous thermal decomposition (retro-Tishchenko reaction) and secondary condensation of the resultant aldehydes. The path from esters to ketones from acidic ester sides is shorter than the one from alcohol ester sides. The mutual proportions of ketones depend also on the control parameters. Springer-Verlag/Akadémiai Kiadó, 2006 esters nationallicence n-butyl cyclopentane-carboxylate nationallicence cyclopentyl n-decanoate nationallicence Ketonization nationallicence Klimkiewicz Roman W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wrocław 2, P.O. Box 1410, Poland aut Grabowska Hanna W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wrocław 2, P.O. Box 1410, Poland aut Syper Ludwik Institute of Organic Chemistry, Biochemistry and Biotechnology, Technical University of Wrocław, 50-370 Wrocław, Wybrzeże Wyspiańskiego 27, Poland aut Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 88/2(2006-08-01), 243-249 0133-1736 88:2<243 2006 88 11144 https://doi.org/10.1007/s11144-006-0058-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-006-0058-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Klimkiewicz Roman W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wrocław 2, P.O. Box 1410, Poland aut NATIONALLICENCE 700 1- Grabowska Hanna W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wrocław 2, P.O. Box 1410, Poland aut NATIONALLICENCE 700 1- Syper Ludwik Institute of Organic Chemistry, Biochemistry and Biotechnology, Technical University of Wrocław, 50-370 Wrocław, Wybrzeże Wyspiańskiego 27, Poland aut NATIONALLICENCE 773 0- Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 88/2(2006-08-01), 243-249 0133-1736 88:2<243 2006 88 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer