caa a22 4500 46788868X CHVBK 20180406152742.0 cr unu---uuuuu 170328e20060401xx s 000 0 eng 10.1007/s11144-006-0040-4 doi (NATIONALLICENCE)springer-10.1007/s11144-006-0040-4 Kinetic analysis of n -butane hydrogenolysis on a Ru/Al2O3catalyst [Elektronische Daten] [Geoffrey C. Bond, Geoffrey C. Bond, Andrew D. Hooper, Andrew D. Hooper] Summary: Analysis of the kinetics of the hydrogenolysis of n-butane on a Ru/Al2O3catalyst permits recognition of the range of H2:n-butane ratio where carbon formation can be neglected. Variation of the apparent activation energy with H2pressure results from a variable contribution of its heat of adsorption to the true activation energy. Effects on product selectivities and on response of rate to H2pressure due to oxidation and low-temperature reduction are also traced to differences in heats of adsorption.</o:p> Springer-Verlag/Akadémiai Kiadó, 2006 ruthenium nationallicence n-butane nationallicence Hydrogenolysis nationallicence Bond Geoffrey C. Brunel University, Uxbridge, UB8 3PH, U.K. aut Hooper Andrew D. Brunel University, Uxbridge, UB8 3PH, U.K. aut Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 87/2(2006-04-01), 325-334 0133-1736 87:2<325 2006 87 11144 https://doi.org/10.1007/s11144-006-0040-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-006-0040-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bond Geoffrey C. Brunel University, Uxbridge, UB8 3PH, U.K aut NATIONALLICENCE 700 1- Hooper Andrew D. Brunel University, Uxbridge, UB8 3PH, U.K aut NATIONALLICENCE 773 0- Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 87/2(2006-04-01), 325-334 0133-1736 87:2<325 2006 87 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer