caa a22 4500 467888728 CHVBK 20180406152742.0 cr unu---uuuuu 170328e20060401xx s 000 0 eng 10.1007/s11144-006-0047-x doi (NATIONALLICENCE)springer-10.1007/s11144-006-0047-x Mechanism of<span style='font-size:10.0pt;font-family:Symbol;mso-bidi-font-family:Symbol'>b-picoline oxidation to nicotinic acid on V-Ti-O catalyst as studied by in situ FTIR<span style='font-size:10.0pt'> [Elektronische Daten] [Galina Ya. Popova, Galina Ya. Popova, Tamara V. Andrushkevich, Tamara V. Andrushkevich, Yuriy A. Chesalov, Yuriy A. Chesalov, Elena V. Ovchinnikova, Elena V. Ovchinnikova] Summary: In situFTIR spectroscopy was used to study the interaction of<span style='font-family:Symbol;mso-bidi-font-family:Symbol'>b-picoline with the surface of a V-Ti-O catalyst in the temperature range of 120-300°C.b-picoline was found to react with the Lewis acid sites of the catalyst to form a nitrogen-coordinated complex. This complex turns into an aldehyde-like complex at</o:p>150-250°C and then into a nicotinate, which is a direct precursor of nicotinic acid.</o:p> Springer-Verlag/Akadémiai Kiadó, 2006 nicotinic acid nationallicence b-picoline nationallicence intermediate nationallicence In situ FTIR spectroscopy nationallicence V-Ti-O catalyst nationallicence Popova Galina Ya Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut Andrushkevich Tamara V. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut Chesalov Yuriy A. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut Ovchinnikova Elena V. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 87/2(2006-04-01), 387-394 0133-1736 87:2<387 2006 87 11144 https://doi.org/10.1007/s11144-006-0047-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-006-0047-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Popova Galina Ya Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut NATIONALLICENCE 700 1- Andrushkevich Tamara V. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut NATIONALLICENCE 700 1- Chesalov Yuriy A. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut NATIONALLICENCE 700 1- Ovchinnikova Elena V. Boreskov Institute of Catalysis, Novosibirsk 630090, Russia aut NATIONALLICENCE 773 0- Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 87/2(2006-04-01), 387-394 0133-1736 87:2<387 2006 87 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer