caa a22 4500 467888906 CHVBK 20180406152742.0 cr unu---uuuuu 170328e20061001xx s 000 0 eng 10.1007/s11144-006-0098-z doi (NATIONALLICENCE)springer-10.1007/s11144-006-0098-z Kinetics and mechanism of the wet oxidation of propene to acetone in the presence of Pd 2+ ions and Mo-V-phosphoric heteropoly acids [Elektronische Daten] [Elena G. Zhizhina, Marina V. Simonova, Viktor F. Odyakov, Klavdiy I. Matveev] Summary: Oxidation of propene to acetone in water solutions in the presence of homogeneous catalysts (Pd2+ + HPA-x, where HPA-x = H3+xPVxMo12-xO40, x = 1-4) is studied. This reaction is shown to be of the 1st order with respect to C3H6 and of the 0.5th order with respect to Pd. The reaction rate does not depend on the concentration of HPA-x and acidity of the catalyst solution. The apparent activation energy of the reaction is 21 kJ/mol. A reaction mechanism is proposed. Springer-Verlag/Akadémiai Kiadó, 2006 Zhizhina Elena G. Boreskov Institute of Catalysis,, Novosibirsk 630090, Russia aut Simonova Marina V. Boreskov Institute of Catalysis,, Novosibirsk 630090, Russia aut Odyakov Viktor F. Boreskov Institute of Catalysis,, Novosibirsk 630090, Russia aut Matveev Klavdiy I. Boreskov Institute of Catalysis,, Novosibirsk 630090, Russia aut Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 89/1(2006-10-01), 157-166 0133-1736 89:1<157 2006 89 11144 https://doi.org/10.1007/s11144-006-0098-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-006-0098-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhizhina Elena G. Boreskov Institute of Catalysis,, Novosibirsk 630090, Russia aut NATIONALLICENCE 700 1- Simonova Marina V. Boreskov Institute of Catalysis,, Novosibirsk 630090, Russia aut NATIONALLICENCE 700 1- Odyakov Viktor F. Boreskov Institute of Catalysis,, Novosibirsk 630090, Russia aut NATIONALLICENCE 700 1- Matveev Klavdiy I. Boreskov Institute of Catalysis,, Novosibirsk 630090, Russia aut NATIONALLICENCE 773 0- Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 89/1(2006-10-01), 157-166 0133-1736 89:1<157 2006 89 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer