caa a22 4500 467889058 CHVBK 20180406152743.0 cr unu---uuuuu 170328e20061001xx s 000 0 eng 10.1007/s11144-006-0079-2 doi (NATIONALLICENCE)springer-10.1007/s11144-006-0079-2 Rate constant for the reaction of OH radicals with CH 3 C(O)Cl determined by direct kinetic method [Elektronische Daten] [Rebeka Nádasdi, István Szilágyi, Gergely Kovács, Sándor Dóbé, Tibor Bérces, Ferenc Márta] Summary: The fast flow technique with OH resonance fluorescence detection has been applied at T = 298 ± 2 K to study the kinetics of the overall reaction: H + CH3C(O)Cl → products (1) A rate constant value of k1 = (1.02 ± 0.12) x 1010 cm3 mol-1 s-1 has been determined which is the first direct kinetic parameter reported for reaction (1) in the literature (the error given refers to 2σ accuracy). Springer-Verlag/Akadémiai Kiadó, 2006 Nádasdi Rebeka Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut Szilágyi István Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut Kovács Gergely Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut Dóbé Sándor Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut Bérces Tibor Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut Márta Ferenc Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 89/1(2006-10-01), 193-199 0133-1736 89:1<193 2006 89 11144 https://doi.org/10.1007/s11144-006-0079-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-006-0079-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Nádasdi Rebeka Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut NATIONALLICENCE 700 1- Szilágyi István Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut NATIONALLICENCE 700 1- Kovács Gergely Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut NATIONALLICENCE 700 1- Dóbé Sándor Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut NATIONALLICENCE 700 1- Bérces Tibor Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut NATIONALLICENCE 700 1- Márta Ferenc Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest, Hungary aut NATIONALLICENCE 773 0- Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 89/1(2006-10-01), 193-199 0133-1736 89:1<193 2006 89 11144 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer