caa a22 4500 467892733 CHVBK 20180406152753.0 cr unu---uuuuu 170328e20060301xx s 000 0 eng 10.1007/s10955-005-9016-4 doi (NATIONALLICENCE)springer-10.1007/s10955-005-9016-4 Configurational Effects in Statistical Theory of Branched Non-Random Polycondensation [Elektronische Daten] [Semion Kuchanov, Konstantin Tarasevich, Timur Zharnikov] The statistical theory of gelation in the simplest process of the non-random polycondensation (S. I. Kuchanov, T. V. Zharnikov, J. Stat. Phys., 111(5/6), 1273 (2003)) has been refined as to be able to take into account the effect of a monomer configuration on topological characteristics of the polymer network of the gel. Proceeding from the kinetic analysis of such a polycondensation, we rigorously prove that it can be described in terms of some stochastic branching process. The parameters of the process depend on the overall number of functional groups in the monomer as well as on the pattern of their mutual arrangement. Examples of some model systems illustrate the effect of kinetic and configurational factors on the topology of a polymer network formed in the course of non-random polycondensation. Springer Science + Business Media, Inc., 2006 gelation nationallicence polymer networks nationallicence statistical kinetics nationallicence stochastic branching process nationallicence Kuchanov Semion Physics Department, Moscow State University, 119992, Moscow, Russia aut Tarasevich Konstantin Physics Department, Moscow State University, 119992, Moscow, Russia aut Zharnikov Timur Nesmeyanov Institute of Elementoorganic Compounds, Vavilov Str., 28, 119991, Moscow, Russia aut Journal of Statistical Physics Springer US; http://www.springer-ny.com 122/5(2006-03-01), 875-908 0022-4715 122:5<875 2006 122 10955 https://doi.org/10.1007/s10955-005-9016-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10955-005-9016-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kuchanov Semion Physics Department, Moscow State University, 119992, Moscow, Russia aut NATIONALLICENCE 700 1- Tarasevich Konstantin Physics Department, Moscow State University, 119992, Moscow, Russia aut NATIONALLICENCE 700 1- Zharnikov Timur Nesmeyanov Institute of Elementoorganic Compounds, Vavilov Str., 28, 119991, Moscow, Russia aut NATIONALLICENCE 773 0- Journal of Statistical Physics Springer US; http://www.springer-ny.com 122/5(2006-03-01), 875-908 0022-4715 122:5<875 2006 122 10955 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer