caa a22 4500 467919801 CHVBK 20180406152913.0 cr unu---uuuuu 170328e20060301xx s 000 0 eng 10.1007/s00706-006-0440-1 doi (NATIONALLICENCE)springer-10.1007/s00706-006-0440-1 Synthesis and Structural Characterization of a New Macrocyclic Polysiloxane-immobilized Ligand System [Elektronische Daten] [Nizam M. El-Ashgar, Issa M. El-Nahhal, Mohamed M. Chehimi, Michel Delamar, Florence Babonneau, Jacques Livage] Summary.: A new porous solid macrocyclic 1,4,7,11,14-pentaazapentadecane-3,15-dione polysiloxane ligand system of the general formula P-(CH2)3-C11H22O2N5 (where P represents [Si-O]n siloxane network) has been prepared by the reaction of polysiloxane-immobilized iminobis(N-(2-aminoethyl)acetamide) with 1,3-dibromopropane. The FTIR and XPS results confirm the introduction of the macrocyclic functional ligand group into the polysiloxane network. The new macrocyclic polysiloxane ligand system exhibits high potential for the uptake of metal ions (Fe3+, Co2+, Ni2+, Cu2+ and Zn2+). Springer-Verlag/Wien, 2006 Keywords. Metal ions uptake nationallicence Ethylenediamine nationallicence Polysiloxanes nationallicence Immobilized P ligand systems nationallicence El-Ashgar Nizam M. Department of Chemistry, The Islamic University of Gaza, P.O. Box 108, Gaza, Palestine aut El-Nahhal Issa M. Department of Chemistry, Al-Azhar University, P.O. Box 1277, Gaza, Palestine aut Chehimi Mohamed M. ITODYS, Université Paris 7 - Denis Diderot and CNRS (UMR 7086), 75005, Paris, France aut Delamar Michel ITODYS, Université Paris 7 - Denis Diderot and CNRS (UMR 7086), 75005, Paris, France aut Babonneau Florence Laboratoire de Chimie de la Matière Condensée, Université Paris VI and CNRS (UMR 7574), 75252, Paris, Cedex 05, France aut Livage Jacques Laboratoire de Chimie de la Matière Condensée, Université Paris VI and CNRS (UMR 7574), 75252, Paris, Cedex 05, France aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/3(2006-03-01), 263-275 0026-9247 137:3<263 2006 137 706 https://doi.org/10.1007/s00706-006-0440-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s00706-006-0440-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- El-Ashgar Nizam M. Department of Chemistry, The Islamic University of Gaza, P.O. Box 108, Gaza, Palestine aut NATIONALLICENCE 700 1- El-Nahhal Issa M. Department of Chemistry, Al-Azhar University, P.O. Box 1277, Gaza, Palestine aut NATIONALLICENCE 700 1- Chehimi Mohamed M. ITODYS, Université Paris 7 - Denis Diderot and CNRS (UMR 7086), 75005, Paris, France aut NATIONALLICENCE 700 1- Delamar Michel ITODYS, Université Paris 7 - Denis Diderot and CNRS (UMR 7086), 75005, Paris, France aut NATIONALLICENCE 700 1- Babonneau Florence Laboratoire de Chimie de la Matière Condensée, Université Paris VI and CNRS (UMR 7574), 75252, Paris, Cedex 05, France aut NATIONALLICENCE 700 1- Livage Jacques Laboratoire de Chimie de la Matière Condensée, Université Paris VI and CNRS (UMR 7574), 75252, Paris, Cedex 05, France aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/3(2006-03-01), 263-275 0026-9247 137:3<263 2006 137 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer