caa a22 4500 467919844 CHVBK 20180406152913.0 cr unu---uuuuu 170328e20060301xx s 000 0 eng 10.1007/s00706-006-0436-x doi (NATIONALLICENCE)springer-10.1007/s00706-006-0436-x Transition Metal Centered Trigonal Prisms as Building Units in Various Rare Earth-Transition Metal-Indides [Elektronische Daten] [Vasyl I. Zaremba, Ute Ch. Rodewald, Mar'yana Lukachuk, Vitaliy P. Dubenskiy, Birgit Heying, Kenichi Katoh, Yuzuru Niide, Akira Ochiai, Rainer Pöttgen] Summary.: The rare earth-transition metal-indides GdPdIn, ErPdIn, YbPdIn, YPtIn, TmPtIn, Dy4Pd10In21, PrPt2In2, and Tb2Pt7In16 were prepared by arc-melting of the elements or by induction melting of the elements in sealed tantalum tubes in a water-cooled sample chamber of a high-frequency furnace. Single crystals of Dy4Pd10In21 and Tb2Pt7In16 were grown through special annealing procedures. The indides were investigated via X-ray powder diffraction and all structures were refined from X-ray single crystal diffractometer data: ZrNiAl type, $P \bar {6}2m$ , a = 767.8(3), c = 390.7(2) pm, wR2 = 0.0722, 356 F2 values for GdPdIn; a = 766.7(3), c = 376.7(1) pm, wR2 = 0.0433, 348 F2 values for ErPdIn; a = 757.2(2), c = 393.59(8) pm, wR2 = 0.0388, 434 F2 values for YbPdIn; a = 758.2(2), c = 384.95(8) pm, wR2 = 0.0643, 353 F2 values for YPtIn; and a = 753.4(1), c = 376.71(4) pm, wR2 = 0.0844, 310 F2 values for TmPtIn, with 14 variable parameters per refinement. Dy4Pd10In21 crystallizes with the monoclinic Ho4Ni10Ga21 structure: C2/m, a = 2284.5(8), b = 441.0(2), c = 1931.4(7) pm, β = 132.74(2)°, wR2 = 0.0419, 1690 F2 values, 112 variable parameters. PrPt2In2 adopts the CePt2In2 type: P21/m, a = 1013.2(3), b = 447.2(3), c = 1019.5(3) pm, β = 116.69(2)°, wR2 = 0.0607, 1259 F2 values, 63 variable parameters. Tb2Pt7In16 is the second representative of the orthorhombic Dy2Pt7In16 type: Cmmm, a = 1211.6(2), b = 1997.1(4), c = 440.52(9) pm, wR2 = 0.0787, 1341 F2 values, 45 variable parameters. The common structural motif of the four different structure types are transition metal centered trigonal prisms formed by the rare earth metal and indium atoms. These prisms are condensed via common corners or via In-In bonds. The crystal chemistry of the four different structure types is discussed. Springer-Verlag/Wien, 2006 Keywords. Rare earth compounds nationallicence Indides nationallicence Crystal chemistry nationallicence Zaremba Vasyl I. Inorganic Chemistry Department, Ivan Franko National University, 79005, Lviv, Ukraine aut Rodewald Ute Ch Institut für Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfälische Wilhelms-Universität Münster, 48149, Münster, Germany aut Lukachuk Mar'yana Max-Plank-Institut für Festkörperforschung, 70569, Stuttgart, Germany aut Dubenskiy Vitaliy P. Inorganic Chemistry Department, Ivan Franko National University, 79005, Lviv, Ukraine aut Heying Birgit Institut für Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfälische Wilhelms-Universität Münster, 48149, Münster, Germany aut Katoh Kenichi Department of Applied Physics, National Defense Academy, 239-8686, Yokosuka, Japan aut Niide Yuzuru Department of Applied Physics, National Defense Academy, 239-8686, Yokosuka, Japan aut Ochiai Akira Center for Low Temperature Science, Tohoku University, 980-8578, Sendai, Japan aut Pöttgen Rainer Institut für Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfälische Wilhelms-Universität Münster, 48149, Münster, Germany aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/3(2006-03-01), 249-261 0026-9247 137:3<249 2006 137 706 https://doi.org/10.1007/s00706-006-0436-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s00706-006-0436-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zaremba Vasyl I. Inorganic Chemistry Department, Ivan Franko National University, 79005, Lviv, Ukraine aut NATIONALLICENCE 700 1- Rodewald Ute Ch Institut für Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfälische Wilhelms-Universität Münster, 48149, Münster, Germany aut NATIONALLICENCE 700 1- Lukachuk Mar'yana Max-Plank-Institut für Festkörperforschung, 70569, Stuttgart, Germany aut NATIONALLICENCE 700 1- Dubenskiy Vitaliy P. Inorganic Chemistry Department, Ivan Franko National University, 79005, Lviv, Ukraine aut NATIONALLICENCE 700 1- Heying Birgit Institut für Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfälische Wilhelms-Universität Münster, 48149, Münster, Germany aut NATIONALLICENCE 700 1- Katoh Kenichi Department of Applied Physics, National Defense Academy, 239-8686, Yokosuka, Japan aut NATIONALLICENCE 700 1- Niide Yuzuru Department of Applied Physics, National Defense Academy, 239-8686, Yokosuka, Japan aut NATIONALLICENCE 700 1- Ochiai Akira Center for Low Temperature Science, Tohoku University, 980-8578, Sendai, Japan aut NATIONALLICENCE 700 1- Pöttgen Rainer Institut für Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfälische Wilhelms-Universität Münster, 48149, Münster, Germany aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/3(2006-03-01), 249-261 0026-9247 137:3<249 2006 137 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer